Bi Mn过共晶合金分别从3个不同状态凝固,合金中MnBi析出相均在磁场作用下以晶体的c轴平行磁场取向,形成规则排列组织,并且所得材料的剩磁都具有明显的各向异性。合金从低于355℃的固液两相区凝固时,铁磁性MnBi析出相在1.0T磁场中迅速... Bi Mn过共晶合金分别从3个不同状态凝固,合金中MnBi析出相均在磁场作用下以晶体的c轴平行磁场取向,形成规则排列组织,并且所得材料的剩磁都具有明显的各向异性。合金从低于355℃的固液两相区凝固时,铁磁性MnBi析出相在1.0T磁场中迅速形成均布的织构组织,并能在无磁场条件下保持稳定,材料无需热处理就有很好的剩磁性能。因此,磁场凝固技术能够高效率地、直接制备出性能优良的MnBi/Bi磁性功能复合材料。展开更多
The solidification structure of Bi-3 wt pct Mn alloy grown up in the semisolid zone under the influence of a staticmagnetic field (up to 1.0 T) and the relation of the magnetic property with the solidification structu...The solidification structure of Bi-3 wt pct Mn alloy grown up in the semisolid zone under the influence of a staticmagnetic field (up to 1.0 T) and the relation of the magnetic property with the solidification structure have beeninvestigated experimentally. It was shown that the primary phase MnBi crystals in the alloy aligned and oriented alongthe direction of the applied magnetic field. The orientating tendency and the average length of the elongated MnBicrystals increased with the increase of the applied field and the solidification time. Moreover, the remanence of thealloy along the aligned direction of the MnBi phase in the case of solidification with a magnetic field was apparentlyanisotropic and nearly double of that without the magnetic field. This indicated that the MnBi crystals orientedand aligned along their easy magnetization axis. A model was proposed to explain the alignment and orientationgrowth of the MnBi crystals in a magnetic field in terms of the magnetic anisotropy of the crystals and the magneticinteraction between them.展开更多
文摘 Bi Mn过共晶合金分别从3个不同状态凝固,合金中MnBi析出相均在磁场作用下以晶体的c轴平行磁场取向,形成规则排列组织,并且所得材料的剩磁都具有明显的各向异性。合金从低于355℃的固液两相区凝固时,铁磁性MnBi析出相在1.0T磁场中迅速形成均布的织构组织,并能在无磁场条件下保持稳定,材料无需热处理就有很好的剩磁性能。因此,磁场凝固技术能够高效率地、直接制备出性能优良的MnBi/Bi磁性功能复合材料。
基金This work was supported by the National Natural Science Foundation of China(No.59871026,50225416,50234020)“Shu Guang”Shanghai Education Development Foundation(No.98SG37).
文摘The solidification structure of Bi-3 wt pct Mn alloy grown up in the semisolid zone under the influence of a staticmagnetic field (up to 1.0 T) and the relation of the magnetic property with the solidification structure have beeninvestigated experimentally. It was shown that the primary phase MnBi crystals in the alloy aligned and oriented alongthe direction of the applied magnetic field. The orientating tendency and the average length of the elongated MnBicrystals increased with the increase of the applied field and the solidification time. Moreover, the remanence of thealloy along the aligned direction of the MnBi phase in the case of solidification with a magnetic field was apparentlyanisotropic and nearly double of that without the magnetic field. This indicated that the MnBi crystals orientedand aligned along their easy magnetization axis. A model was proposed to explain the alignment and orientationgrowth of the MnBi crystals in a magnetic field in terms of the magnetic anisotropy of the crystals and the magneticinteraction between them.
