Filler cleaning is a challenge that affects the efficient separation of FCCS particles by electrostatic methods and limits the utilization of the oil slurry.Two filler cleaning methods are proposed in this paper,the f...Filler cleaning is a challenge that affects the efficient separation of FCCS particles by electrostatic methods and limits the utilization of the oil slurry.Two filler cleaning methods are proposed in this paper,the flushing desorption method and the electrostatic desorption method,where desorption is achieved by respectively applying a flow field or an electric field to the fillers immersed in a cleaning solution(ethyl acetate).Also,the“rough particle-smooth plane”contact model between particles and filler was established,and the particle force model was established by analyzing the movement of particles in the process of cleaning.Furthermore,combining the established contact model and force model,the detachment model of particles was proposed.In this model,the dimensionless numberλis used to discriminate the attachment state of particles whose validity was verified by experiments.The experimental results showed that the cleaning efficiency of flushing desorption method and electrostatic desorption method increase with the increase of flow rate and voltage,which reached 50.5%and 61.4%at 0.1 m/s and 14 kV.展开更多
Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS)...Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS).The catalyst particles in FCCS seriously restrict the secondary processing of FCCS and need to be removed,and the properties of Fccs is an important factor that affects the removal efficiency of the catalyst particles.Based on the"effective contact point"model proposed by the research group,this study further proposed the"electrostatic separation efficiency calculation"model.In this model,since Fccs has a uniform distribution of catalyst particles,the ratio of the number of catalyst particles can be expressed as the ratio of area to achieve the calculation of separation efficiency.Then the catalyst removal efficiency under different viscosity was analyzed,thus verifying the feasibility of this model.The effects of temperature and mass ratio of four components on the viscosity of FccS were investigated respectively,then the effects of temperature and four components'mass ratio on the electrostatic sep-aration can be directly converted into the effect of viscosity on the electrostatic separation efficiency.All the results show the electrostatic separation efficiency decreases with increasing viscosity,and the best separationtemperatureis120℃.展开更多
Petroleum-based polycyclic aromatic hydrocarbons(PAHs),as by-products of petroleum,offer the advantages of abundant availability and high carbon content,making them ideal high-quality raw materials for the fabrication...Petroleum-based polycyclic aromatic hydrocarbons(PAHs),as by-products of petroleum,offer the advantages of abundant availability and high carbon content,making them ideal high-quality raw materials for the fabrication of carbon anode materials in lithium batteries(LIBs).This study presents a novel,dual-purpose strategy to fabricate hollow core–shell silicon-carbon composites(Si@Void@Cx)via the in-situ catalytic polycondensation of Fluid Catalytic Cracking(FCC)slurry.Unlike traditional synthesis routes employing metallic Lewis acids(e.g.,AlCl_(3),FeCl_(3)),silicon tetrachloride(SiCl_(4))was used as a cleaner,bifunctional catalyst that avoids metallic contamination while facilitating the precise polymerization of the carbon matrix.This approach not only circumvents the integration of heteroatoms via the catalyst,but also simplifies the process flow,reduces energy consumption,and contributes to a greener,sustainable technology by enhancing the high-value utilization of FCC,benefiting both resource conservation and environmental protection.The optimized composite(Si@Void@C1)delivers a robust electrochemical performance,exhibiting a specific capacity of 601.9 mAh/g and maintaining electrode integrity with a negligible thickness expansion of only 7%after 1000 cycles.Si@Void@C1 capitalizes on the well-dispersed silicon(Si)nanoparticles and the intact hollow core–shell structure to effectively buffer against the volume expansion stress of Si,thus maintaining electrode structural integrity and achieving superior cycling performance.This work provides a scalable,sustainable pathway for transforming petrochemical byproducts into advanced energy storage materials.展开更多
摩尔体积的可靠预测对高熵合金设计具有重要意义。然而,由于受试验数据的限制,基于相图热力学计算(computational coupling of phase diagram and thermochemistry,CALPHAD)方法的多组元体系摩尔体积数据库的发展缓慢。为此,将第一性原...摩尔体积的可靠预测对高熵合金设计具有重要意义。然而,由于受试验数据的限制,基于相图热力学计算(computational coupling of phase diagram and thermochemistry,CALPHAD)方法的多组元体系摩尔体积数据库的发展缓慢。为此,将第一性原理计算与CALPHAD方法相结合,通过拟合第一性原理计算得到的摩尔体积确定模型参数,从而减少CALPHAD方法对试验数据的依赖,成功构建了Al CoCrFeMnNi六元系FCC溶体相的常温常压摩尔体积模型及数据库。在数据库构建过程中,通过试验数据对第一性原理计算结果进行校正以消除系统误差,校正结果与试验数据总体吻合较好。随后确定了模型参数,拟合了所有子二元系及部分子三元系的摩尔体积第一性原理校正结果和可用试验数据。最后,基于所构建的数据库对FeNiCoMn、CrNiCoMn和FeNiCoCrMn等原子比合金的摩尔体积进行预测,预测结果与第一性原理校正结果较吻合。展开更多
基金funded by the National Natural Science foundation of China(No.52476043).
文摘Filler cleaning is a challenge that affects the efficient separation of FCCS particles by electrostatic methods and limits the utilization of the oil slurry.Two filler cleaning methods are proposed in this paper,the flushing desorption method and the electrostatic desorption method,where desorption is achieved by respectively applying a flow field or an electric field to the fillers immersed in a cleaning solution(ethyl acetate).Also,the“rough particle-smooth plane”contact model between particles and filler was established,and the particle force model was established by analyzing the movement of particles in the process of cleaning.Furthermore,combining the established contact model and force model,the detachment model of particles was proposed.In this model,the dimensionless numberλis used to discriminate the attachment state of particles whose validity was verified by experiments.The experimental results showed that the cleaning efficiency of flushing desorption method and electrostatic desorption method increase with the increase of flow rate and voltage,which reached 50.5%and 61.4%at 0.1 m/s and 14 kV.
基金supported by the[Natural Science Foundation Project of Shandong Province#1]under Grant[ZR2019MEE033][Fundamental Research Funds for the central Universities#2]under Grant[19CX02035A].
文摘Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS).The catalyst particles in FCCS seriously restrict the secondary processing of FCCS and need to be removed,and the properties of Fccs is an important factor that affects the removal efficiency of the catalyst particles.Based on the"effective contact point"model proposed by the research group,this study further proposed the"electrostatic separation efficiency calculation"model.In this model,since Fccs has a uniform distribution of catalyst particles,the ratio of the number of catalyst particles can be expressed as the ratio of area to achieve the calculation of separation efficiency.Then the catalyst removal efficiency under different viscosity was analyzed,thus verifying the feasibility of this model.The effects of temperature and mass ratio of four components on the viscosity of FccS were investigated respectively,then the effects of temperature and four components'mass ratio on the electrostatic sep-aration can be directly converted into the effect of viscosity on the electrostatic separation efficiency.All the results show the electrostatic separation efficiency decreases with increasing viscosity,and the best separationtemperatureis120℃.
基金financially supported by National Key Research and Development Program of China(2022YFB3504000)the National Natural Science Foundation of China(22508430).
文摘Petroleum-based polycyclic aromatic hydrocarbons(PAHs),as by-products of petroleum,offer the advantages of abundant availability and high carbon content,making them ideal high-quality raw materials for the fabrication of carbon anode materials in lithium batteries(LIBs).This study presents a novel,dual-purpose strategy to fabricate hollow core–shell silicon-carbon composites(Si@Void@Cx)via the in-situ catalytic polycondensation of Fluid Catalytic Cracking(FCC)slurry.Unlike traditional synthesis routes employing metallic Lewis acids(e.g.,AlCl_(3),FeCl_(3)),silicon tetrachloride(SiCl_(4))was used as a cleaner,bifunctional catalyst that avoids metallic contamination while facilitating the precise polymerization of the carbon matrix.This approach not only circumvents the integration of heteroatoms via the catalyst,but also simplifies the process flow,reduces energy consumption,and contributes to a greener,sustainable technology by enhancing the high-value utilization of FCC,benefiting both resource conservation and environmental protection.The optimized composite(Si@Void@C1)delivers a robust electrochemical performance,exhibiting a specific capacity of 601.9 mAh/g and maintaining electrode integrity with a negligible thickness expansion of only 7%after 1000 cycles.Si@Void@C1 capitalizes on the well-dispersed silicon(Si)nanoparticles and the intact hollow core–shell structure to effectively buffer against the volume expansion stress of Si,thus maintaining electrode structural integrity and achieving superior cycling performance.This work provides a scalable,sustainable pathway for transforming petrochemical byproducts into advanced energy storage materials.
文摘摩尔体积的可靠预测对高熵合金设计具有重要意义。然而,由于受试验数据的限制,基于相图热力学计算(computational coupling of phase diagram and thermochemistry,CALPHAD)方法的多组元体系摩尔体积数据库的发展缓慢。为此,将第一性原理计算与CALPHAD方法相结合,通过拟合第一性原理计算得到的摩尔体积确定模型参数,从而减少CALPHAD方法对试验数据的依赖,成功构建了Al CoCrFeMnNi六元系FCC溶体相的常温常压摩尔体积模型及数据库。在数据库构建过程中,通过试验数据对第一性原理计算结果进行校正以消除系统误差,校正结果与试验数据总体吻合较好。随后确定了模型参数,拟合了所有子二元系及部分子三元系的摩尔体积第一性原理校正结果和可用试验数据。最后,基于所构建的数据库对FeNiCoMn、CrNiCoMn和FeNiCoCrMn等原子比合金的摩尔体积进行预测,预测结果与第一性原理校正结果较吻合。
