Rare earth high-entropy alloys(RE-HEAs)exhibit great potential to be applied as refrigerants due to their good comprehensive magnetocaloric properties.In this work,octary GdTbDyHoErTmCoAl and GdTbDyHoErTmCoNi RE-HEAs ...Rare earth high-entropy alloys(RE-HEAs)exhibit great potential to be applied as refrigerants due to their good comprehensive magnetocaloric properties.In this work,octary GdTbDyHoErTmCoAl and GdTbDyHoErTmCoNi RE-HEAs with amorphous/nanocrystalline structure exhibiting comparable magnetocaloric effect were synthesized.Both RE-HEAs show a second-order magnetic phase transition in the temperature range of hydrogen liquefaction.Due to the complex magnetic interactions,a spin glasslike behavior at low temperatures is observed in the RE-HEAs.A superior magnetocaloric effect is obtained in the nanocrystalline GdTbDyHoErTmCoNi high-entropy alloy that is multiphase attributed to a stronger magnetic exchange interaction when compared with the other that exhibits single amorphous structure.Despite heterogeneous microstructure,homogeneous chemical distributions are observed in the partially crystallized high-entropy alloy.In addition,the magnetocaloric effect and magnetic transition behavior of rare earth medium-and high-entropy alloys,including the RE-HEAs in this study,are summarized and discussed.The results in this work provide a helpful guide for the design of RE-HEAs for hydrogen liquefaction applications with excellent magnetocaloric effects.展开更多
A new fluorescent probe,DQCd2,based on 4-piperidinoquinoline has been synthesized as a fluorescent probe for Cd^2＋.It can ratiometrically respond to Cd^2＋ in PBS buffer by a remarkable emission intensity enhancement...A new fluorescent probe,DQCd2,based on 4-piperidinoquinoline has been synthesized as a fluorescent probe for Cd^2＋.It can ratiometrically respond to Cd^2＋ in PBS buffer by a remarkable emission intensity enhancement（88-fold） and wavelength shift（70 nm）.展开更多
In the process of tunneling of tunnel boring machine (TBM), different geological conditions often correspond to different working conditions, and the randomness of geological conditions also causes the order of occurr...In the process of tunneling of tunnel boring machine (TBM), different geological conditions often correspond to different working conditions, and the randomness of geological conditions also causes the order of occurrence of each working condition to be different. Under the conversion of different working conditions, this makes the vibration of different types of cutterheads different. How to choose the appropriate type of cutterhead according to different geological conditions is very important for saving engineering cost and increasing cutterhead life. In view of the above situation, this paper proposes a stability evaluation method during the TBM tunneling process to select the appropriate cutterhead type. Firstly, the corresponding relationship between geology and working conditions is established according to different geological conditions, and the input loads corresponding to geological conditions are obtained. Then, it is substituted into the dynamic model of the cutterhead system, the vibration response boundaries of each degree of freedom are obtained by solving. And the average value of the maximum boundary amplitude of each degree of freedom is taken to represent the extreme vibration of the cutterhead under the corresponding working conditions. Finally, by comparing the fluctuation of the ultimate vibration amplitude of each type of cutterhead in the process of working condition conversion, the results are as follows: when the transition between homogeneous strata and composite strata is normal and there is no large turning and deviation correction, the vibration response of the two-part cutterhead is the smallest, and the two-part cutterhead is the best choice. Otherwise, the five-part cutterhead is the best choice, while the stability of the integrated cutterhead is the worst.展开更多
基金Project supported by the National Natural Science Foundation of China(52101193,51975183)China Postdoctoral Science Foundation(2022M711002)+2 种基金Fundamental Research Funds for the Central Universities(B220202036)the Natural Science Foundation of Jiangsu Province(BK20201316)Jiangsu Planned Projects for Postdoctoral Research Funds(2021K646C)。
文摘Rare earth high-entropy alloys(RE-HEAs)exhibit great potential to be applied as refrigerants due to their good comprehensive magnetocaloric properties.In this work,octary GdTbDyHoErTmCoAl and GdTbDyHoErTmCoNi RE-HEAs with amorphous/nanocrystalline structure exhibiting comparable magnetocaloric effect were synthesized.Both RE-HEAs show a second-order magnetic phase transition in the temperature range of hydrogen liquefaction.Due to the complex magnetic interactions,a spin glasslike behavior at low temperatures is observed in the RE-HEAs.A superior magnetocaloric effect is obtained in the nanocrystalline GdTbDyHoErTmCoNi high-entropy alloy that is multiphase attributed to a stronger magnetic exchange interaction when compared with the other that exhibits single amorphous structure.Despite heterogeneous microstructure,homogeneous chemical distributions are observed in the partially crystallized high-entropy alloy.In addition,the magnetocaloric effect and magnetic transition behavior of rare earth medium-and high-entropy alloys,including the RE-HEAs in this study,are summarized and discussed.The results in this work provide a helpful guide for the design of RE-HEAs for hydrogen liquefaction applications with excellent magnetocaloric effects.
基金the National Natural Science Foundation of China (Nos.21102148,21125205,212210017)National Basic Research Program of China(Nos.2009CB930802,2011CB935800)the State Key Laboratory of Fine Chemicals,Department of Chemical Engineering,Dalian University of Technology for financial supports
文摘A new fluorescent probe,DQCd2,based on 4-piperidinoquinoline has been synthesized as a fluorescent probe for Cd^2＋.It can ratiometrically respond to Cd^2＋ in PBS buffer by a remarkable emission intensity enhancement（88-fold） and wavelength shift（70 nm）.
基金National Natural Science Foundation of China(Grant No. 51875076) NSFC-Liaoning United Key fund (Grant No. U1708255).
文摘In the process of tunneling of tunnel boring machine (TBM), different geological conditions often correspond to different working conditions, and the randomness of geological conditions also causes the order of occurrence of each working condition to be different. Under the conversion of different working conditions, this makes the vibration of different types of cutterheads different. How to choose the appropriate type of cutterhead according to different geological conditions is very important for saving engineering cost and increasing cutterhead life. In view of the above situation, this paper proposes a stability evaluation method during the TBM tunneling process to select the appropriate cutterhead type. Firstly, the corresponding relationship between geology and working conditions is established according to different geological conditions, and the input loads corresponding to geological conditions are obtained. Then, it is substituted into the dynamic model of the cutterhead system, the vibration response boundaries of each degree of freedom are obtained by solving. And the average value of the maximum boundary amplitude of each degree of freedom is taken to represent the extreme vibration of the cutterhead under the corresponding working conditions. Finally, by comparing the fluctuation of the ultimate vibration amplitude of each type of cutterhead in the process of working condition conversion, the results are as follows: when the transition between homogeneous strata and composite strata is normal and there is no large turning and deviation correction, the vibration response of the two-part cutterhead is the smallest, and the two-part cutterhead is the best choice. Otherwise, the five-part cutterhead is the best choice, while the stability of the integrated cutterhead is the worst.
