Three copper(Ⅱ),nickel and cadmium(Ⅱ)complexes,namely[Cu_(2)(μ-H2dbda)2(phen)2]·2H_(2)O(1),[Ni(μ-H2dbda)(μ-bpb)(H_(2)O)2]n(2),and[Cd(μ-H2dbda)(μ-bpa)]n(3),have been constructed hydrothermally using H4dbda(...Three copper(Ⅱ),nickel and cadmium(Ⅱ)complexes,namely[Cu_(2)(μ-H2dbda)2(phen)2]·2H_(2)O(1),[Ni(μ-H2dbda)(μ-bpb)(H_(2)O)2]n(2),and[Cd(μ-H2dbda)(μ-bpa)]n(3),have been constructed hydrothermally using H4dbda(4,4'-dihydroxy-[1,1'-biphenyl]-3,3'-dicarboxylic acid),phen(1,10-phenanthroline),bpb(1,4-bis(pyrid-4-yl)benzene),bpa(bis(4-pyridyl)amine),and copper,nickel and cadmium chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and singlecrystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three complexes crystallize in the monoclinic P21/n,tetragonal I42d,and orthorhombic P21212 space groups.The complexes exhibit molecular dimers(1)or 2D metal-organic networks(2 and 3).The catalytic performances in the Knoevenagel reaction of these complexes were investigated.Complex 1 exhibits an effective catalytic activity and excellent reusability as a heterogeneous catalyst in the Knoevenagel reaction at room temperature.CCDC:2463800,1;2463801,2;2463802,3.展开更多
Energy-saving buildings(ESBs)are an emerging green technology that can significantly reduce building-associated cooling and heating energy consumption,catering to the desire for carbon neutrality and sustainable devel...Energy-saving buildings(ESBs)are an emerging green technology that can significantly reduce building-associated cooling and heating energy consumption,catering to the desire for carbon neutrality and sustainable development of society.Smart photovoltaic windows(SPWs)offer a promising platform for designing ESBs because they present the capability to regulate and harness solar energy.With frequent outbreaks of extreme weather all over the world,the achievement of exceptional energy-saving effect under different weather conditions is an inevitable trend for the development of ESBs but is hardly achieved via existing SPWs.Here,we substantially reduce the driving voltage of polymerdispersed liquid crystals(PDLCs)by 28.1%via molecular engineering while maintaining their high solar transmittance(T_(sol)=83.8%,transparent state)and solar modulating ability(ΔT_(sol)=80.5%).By the assembly of perovskite solar cell and a broadband thermal-managing unit encompassing the electrical-responsive PDLCs,transparent high-emissivity SiO_(2) passive radiation-cooling,and Ag low-emissivity layers possesses,we present a tri-band regulation and split-type SPW possessing superb energy-saving effect in all-season.The perovskite solar cell can produce the electric power to stimulate the electrical-responsive behavior of the PDLCs,endowing the SPWs zero-energy input solar energy regulating characteristic,and compensate the daily energy consumption needed for ESBs.Moreover,the scalable manufacturing technology holds a great potential for the real-world applications.展开更多
With the approval of more and more genetically modified(GM)crops in our country,GM safety management has become more important.Transgenic detection is a major approach for transgenic safety management.Nevertheless,a c...With the approval of more and more genetically modified(GM)crops in our country,GM safety management has become more important.Transgenic detection is a major approach for transgenic safety management.Nevertheless,a convenient and visual technique with low equipment requirements and high sensitivity for the field detection of GM plants is still lacking.On the basis of the existing recombinase polymerase amplification(RPA)technique,we developed a multiplex RPA(multi-RPA)method that can simultaneously detect three transgenic elements,including the cauliflower mosaic virus 35S gene(CaMV35S)promoter,neomycin phosphotransferaseⅡgene(NptⅡ)and hygromycin B phosphotransferase gene(Hyg),thus improving the detection rate.Moreover,we coupled this multi-RPA technique with the CRISPR/Cas12a reporter system,which enabled the detection results to be clearly observed by naked eyes under ultraviolet(UV)light(254 nm;which could be achieved by a portable UV flashlight),therefore establishing a multi-RPA visual detection technique.Compared with the traditional test strip detection method,this multi-RPA-CRISPR/Cas12a technique has the higher specificity,higher sensitivity,wider application range and lower cost.Compared with other polymerase chain reaction(PCR)techniques,it also has the advantages of low equipment requirements and visualization,making it a potentially feasible method for the field detection of GM plants.展开更多
This study proposes a framework for the concept of“new quality productive forces”in the ice and snow economy(ISE)as a strategic response to global climate change and the demands of technological and industrial trans...This study proposes a framework for the concept of“new quality productive forces”in the ice and snow economy(ISE)as a strategic response to global climate change and the demands of technological and industrial transformation for high-quality development.These new quality productive forces in the ISE have developed alongside the zonal distribution of natural resources,strictly adhere to ecological principles,and integrate value transformation mechanisms specific to ice and snow resources.Their development is projected to generate multiple benefits across ecological,economic,and social dimensions.The new quality productive forces in the ISE are characterized by technology-driven resource development,synergistic integration across the entire ice and snow industry value chain,and a focus on high-quality,green growth.Grounded in geography and economics,the new quality productive forces in the ISE link scientific innovation,the reallocation of productive factors,and industrial upgrading within the context of resource constraints.Furthermore,they expand the growth potential of the ISE by fostering new production relations through digital,intelligent,and green integration,while advancing low-carbon,sustainable development under the guiding principle that“ice and snow landscapes are also mountains of gold and silver.”For China's ISE,these new quality productive forces emphasize rigorous resource protection,balanced human-environment relationships,a resilient integrated supply chain framework,and an efficient“dual circulation”economic model.Practical strategies include integrating production factors,optimizing spatial resource allocation,fostering industrial synergy,and adapting production relations,all aimed at advancing the sustainable and high-quality development of China's ISE.展开更多
The Upper Cretaceous of Tantou Basin in western Henan has yielded many vertebrate fossils,which are featured by several non-avian dinosaurs.Meanwhile,studies on their eggs were yet inadequate though many eggshells hav...The Upper Cretaceous of Tantou Basin in western Henan has yielded many vertebrate fossils,which are featured by several non-avian dinosaurs.Meanwhile,studies on their eggs were yet inadequate though many eggshells have been reported.The newly discovered material 41HⅤ0199 was excavated from the Upper Cretaceous Qiupa Formation in 2021.The block preserves eight complete eggs arranged in two partial rings that form a partial clutch,and there are some scattered eggshells preserved closely with the block,showing a concave-up to concave-down ratio of 54.5:45.5,which indicates that the scattered eggshells come from the clutch and the clutch had been partially broken before it was buried.Based on morphological and microstructural characteristics,the eggs and eggshells can be assigned to Macroolithus yaotunensis(Elongatoolithidae),an oospecies known to be related to oviraptorids,which leads Yulong mini to be its probable producer.Besides,some eggshells show microstructural signs indicating egg retention,which marks the second example of egg retention in the oofamily Elongatoolithidae.展开更多
During strike-slip fault dislocation,multiple fault planes are commonly observed.The resulting permanent ground deformation can lead to profound structural damage to tunnels.However,existing analytical models do not c...During strike-slip fault dislocation,multiple fault planes are commonly observed.The resulting permanent ground deformation can lead to profound structural damage to tunnels.However,existing analytical models do not consider multiple fault planes.Instead,they concentrate the entire fault displacement onto a single fault plane for analysis,thereby giving rise to notable errors in the calculated results.To address this issue,a refined nonlinear theoretical model was established to analyze the mechanical responses of the tunnels subjected to multiple strike-slip fault dislocations.The analytical model considers the number of fault planes,nonlinear soil‒tunnel interactions,geometric nonlinearity,and fault zone width,leading to a significant improvement in its range of applicability and calculation accuracy.The results of the analytical model are in agreement,both qualitatively and quantitatively,with the model test and numerical results.Then,based on the proposed theoretical model,a sensitivity analysis of parameters was conducted,focusing on the variables such as the number of fault planes,fault plane distance(d),fault displacement ratio(η),burial depth(C),crossing angle(β),tunnel diameter(D),fault zone width(Wf),and strike-slip fault displacement(Δfs).The results show that the peak shear force(Vmax),bending moment(Mmax),and axial force(Nmax)decrease with increasing d.The Vmax of the tunnel is found at the fault plane with the largest fault displacement.C,D,andΔfs contribute to the increases in Vmax,Mmax,and Nmax.Additionally,increasing the number of fault planes reduces Vmax and Mmax,whereas the variation in Nmax remains minimal.展开更多
Mercury ions(Hg^(2+))and bacteria are widely spread in water pollution and pose a great threat to human health and the environment.Herein,a multifunctional COF Dmta Tph with significant Hg^(2+)adsorption capability an...Mercury ions(Hg^(2+))and bacteria are widely spread in water pollution and pose a great threat to human health and the environment.Herein,a multifunctional COF Dmta Tph with significant Hg^(2+)adsorption capability and continuous sunlight-driven sterilization property is designed and synthesized by introducing thioether and photosensitive porphyrin in a single molecule.The obtained COF displays a high Hg^(2+)adsorption capacity of 657.9 mg/g at 298 K and a superior antibacterial effect toward Escherichia coli and Staphylococcus aureus under sunlight irradiation.Mechanistic studies reveal that the strong coordination between S species and Hg^(2+)is the main driving force for high Hg^(2+)adsorption capability.The sterilization mechanism clarifies that the inactivation of bacteria is caused by1O_(2)produced from Dmta Tph with the assistance of light irradiation.Noteworthy,when Dmta Tph is applied in the treatment of wastewater,it displays high Hg^(2+)removal efficiency and remarkable antibacterial effect under complex conditions.This study has demonstrated a promising strategy for designing multifunctional COF-based materials,offering great potential in tackling the problem of heavy metal ions and bacteria pollution in water.展开更多
The origins of peloidal micrites in reefal limestone are not yet well understood.Moscovian microbial reefs with abundant peloidal micrites from Guizhou,South China,provide an opportunity to study the peloids and their...The origins of peloidal micrites in reefal limestone are not yet well understood.Moscovian microbial reefs with abundant peloidal micrites from Guizhou,South China,provide an opportunity to study the peloids and their geological significance for this time interval.Three types of peloids are differentiated:microbial,lithic,and bioclastic peloids.Microbial peloids that are well-sorted and may form in situ by microbial activities.The poorly sorted lithic peloids are derived from erosion and redeposition of the micrite matrix caused by the bottom turbulence induced by periodic storms.Bioclastic peloids are completely micritized fragments of hard parts and shells.Microbial boring and encrustations promote the processes of micritization.Microbial peloids commonly develop in zones with low or normal energy levels,and contribute to the construction and stabilization of the framework.In contrast,the occurrence of lithic peloids reflects that the reefs are destroyed by bottom turbulence during growth.It is suggested that the microbial reefs were deposited under a dynamic balance between constructional versus destructive processes.By comparative analysis,the peloids as microbial in origin play a key role in the growth and stabilization of bioconstructions during Carboniferous,which should be paid more attention in the studies of Carboniferous buildups.展开更多
文摘Three copper(Ⅱ),nickel and cadmium(Ⅱ)complexes,namely[Cu_(2)(μ-H2dbda)2(phen)2]·2H_(2)O(1),[Ni(μ-H2dbda)(μ-bpb)(H_(2)O)2]n(2),and[Cd(μ-H2dbda)(μ-bpa)]n(3),have been constructed hydrothermally using H4dbda(4,4'-dihydroxy-[1,1'-biphenyl]-3,3'-dicarboxylic acid),phen(1,10-phenanthroline),bpb(1,4-bis(pyrid-4-yl)benzene),bpa(bis(4-pyridyl)amine),and copper,nickel and cadmium chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and singlecrystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three complexes crystallize in the monoclinic P21/n,tetragonal I42d,and orthorhombic P21212 space groups.The complexes exhibit molecular dimers(1)or 2D metal-organic networks(2 and 3).The catalytic performances in the Knoevenagel reaction of these complexes were investigated.Complex 1 exhibits an effective catalytic activity and excellent reusability as a heterogeneous catalyst in the Knoevenagel reaction at room temperature.CCDC:2463800,1;2463801,2;2463802,3.
基金supported by Natural Science Foundation of China(Grant No.52372076,52073081,52203322,5252200843)Ministry of Science and Technology of the People’s Republic of China(2023YFB3812800)Fundamental Research Funds for the Central Universities(FRF-TP-25-073)。
文摘Energy-saving buildings(ESBs)are an emerging green technology that can significantly reduce building-associated cooling and heating energy consumption,catering to the desire for carbon neutrality and sustainable development of society.Smart photovoltaic windows(SPWs)offer a promising platform for designing ESBs because they present the capability to regulate and harness solar energy.With frequent outbreaks of extreme weather all over the world,the achievement of exceptional energy-saving effect under different weather conditions is an inevitable trend for the development of ESBs but is hardly achieved via existing SPWs.Here,we substantially reduce the driving voltage of polymerdispersed liquid crystals(PDLCs)by 28.1%via molecular engineering while maintaining their high solar transmittance(T_(sol)=83.8%,transparent state)and solar modulating ability(ΔT_(sol)=80.5%).By the assembly of perovskite solar cell and a broadband thermal-managing unit encompassing the electrical-responsive PDLCs,transparent high-emissivity SiO_(2) passive radiation-cooling,and Ag low-emissivity layers possesses,we present a tri-band regulation and split-type SPW possessing superb energy-saving effect in all-season.The perovskite solar cell can produce the electric power to stimulate the electrical-responsive behavior of the PDLCs,endowing the SPWs zero-energy input solar energy regulating characteristic,and compensate the daily energy consumption needed for ESBs.Moreover,the scalable manufacturing technology holds a great potential for the real-world applications.
基金the Experimental Technology Research Project of Zhejiang University(SYB202138)National Natural Science Foundation of China(32000195)。
文摘With the approval of more and more genetically modified(GM)crops in our country,GM safety management has become more important.Transgenic detection is a major approach for transgenic safety management.Nevertheless,a convenient and visual technique with low equipment requirements and high sensitivity for the field detection of GM plants is still lacking.On the basis of the existing recombinase polymerase amplification(RPA)technique,we developed a multiplex RPA(multi-RPA)method that can simultaneously detect three transgenic elements,including the cauliflower mosaic virus 35S gene(CaMV35S)promoter,neomycin phosphotransferaseⅡgene(NptⅡ)and hygromycin B phosphotransferase gene(Hyg),thus improving the detection rate.Moreover,we coupled this multi-RPA technique with the CRISPR/Cas12a reporter system,which enabled the detection results to be clearly observed by naked eyes under ultraviolet(UV)light(254 nm;which could be achieved by a portable UV flashlight),therefore establishing a multi-RPA visual detection technique.Compared with the traditional test strip detection method,this multi-RPA-CRISPR/Cas12a technique has the higher specificity,higher sensitivity,wider application range and lower cost.Compared with other polymerase chain reaction(PCR)techniques,it also has the advantages of low equipment requirements and visualization,making it a potentially feasible method for the field detection of GM plants.
基金The Third Scientific Expedition Project in Xinjiang,No.2022xjkk0905Project Commissioned by the General Administration of Sport of ChinaProject Commissioned by the Ministry of Culture and Tourism of the People’s Republic of China。
文摘This study proposes a framework for the concept of“new quality productive forces”in the ice and snow economy(ISE)as a strategic response to global climate change and the demands of technological and industrial transformation for high-quality development.These new quality productive forces in the ISE have developed alongside the zonal distribution of natural resources,strictly adhere to ecological principles,and integrate value transformation mechanisms specific to ice and snow resources.Their development is projected to generate multiple benefits across ecological,economic,and social dimensions.The new quality productive forces in the ISE are characterized by technology-driven resource development,synergistic integration across the entire ice and snow industry value chain,and a focus on high-quality,green growth.Grounded in geography and economics,the new quality productive forces in the ISE link scientific innovation,the reallocation of productive factors,and industrial upgrading within the context of resource constraints.Furthermore,they expand the growth potential of the ISE by fostering new production relations through digital,intelligent,and green integration,while advancing low-carbon,sustainable development under the guiding principle that“ice and snow landscapes are also mountains of gold and silver.”For China's ISE,these new quality productive forces emphasize rigorous resource protection,balanced human-environment relationships,a resilient integrated supply chain framework,and an efficient“dual circulation”economic model.Practical strategies include integrating production factors,optimizing spatial resource allocation,fostering industrial synergy,and adapting production relations,all aimed at advancing the sustainable and high-quality development of China's ISE.
文摘The Upper Cretaceous of Tantou Basin in western Henan has yielded many vertebrate fossils,which are featured by several non-avian dinosaurs.Meanwhile,studies on their eggs were yet inadequate though many eggshells have been reported.The newly discovered material 41HⅤ0199 was excavated from the Upper Cretaceous Qiupa Formation in 2021.The block preserves eight complete eggs arranged in two partial rings that form a partial clutch,and there are some scattered eggshells preserved closely with the block,showing a concave-up to concave-down ratio of 54.5:45.5,which indicates that the scattered eggshells come from the clutch and the clutch had been partially broken before it was buried.Based on morphological and microstructural characteristics,the eggs and eggshells can be assigned to Macroolithus yaotunensis(Elongatoolithidae),an oospecies known to be related to oviraptorids,which leads Yulong mini to be its probable producer.Besides,some eggshells show microstructural signs indicating egg retention,which marks the second example of egg retention in the oofamily Elongatoolithidae.
基金support from the National Natural Science Foundation of China(Grant Nos.52378411,52208404)China National Railway Group Limited Science and Technology Research and Development Program(Grant No.K2023G041).
文摘During strike-slip fault dislocation,multiple fault planes are commonly observed.The resulting permanent ground deformation can lead to profound structural damage to tunnels.However,existing analytical models do not consider multiple fault planes.Instead,they concentrate the entire fault displacement onto a single fault plane for analysis,thereby giving rise to notable errors in the calculated results.To address this issue,a refined nonlinear theoretical model was established to analyze the mechanical responses of the tunnels subjected to multiple strike-slip fault dislocations.The analytical model considers the number of fault planes,nonlinear soil‒tunnel interactions,geometric nonlinearity,and fault zone width,leading to a significant improvement in its range of applicability and calculation accuracy.The results of the analytical model are in agreement,both qualitatively and quantitatively,with the model test and numerical results.Then,based on the proposed theoretical model,a sensitivity analysis of parameters was conducted,focusing on the variables such as the number of fault planes,fault plane distance(d),fault displacement ratio(η),burial depth(C),crossing angle(β),tunnel diameter(D),fault zone width(Wf),and strike-slip fault displacement(Δfs).The results show that the peak shear force(Vmax),bending moment(Mmax),and axial force(Nmax)decrease with increasing d.The Vmax of the tunnel is found at the fault plane with the largest fault displacement.C,D,andΔfs contribute to the increases in Vmax,Mmax,and Nmax.Additionally,increasing the number of fault planes reduces Vmax and Mmax,whereas the variation in Nmax remains minimal.
基金financially supported by the National Natural Science Foundation of China(Nos.22106078,62105175)High-end Foreign Experts Recruitment Plan(No.G2023024007L)+1 种基金Shandong Provincial Natural Science Foundation(Nos.ZR2022YQ12,ZR2021QB031,ZR2021QF058)the Science,Education,and Industry Integration Pilot Project for Talent Research at Qilu University of Technology(Shandong Academy of Sciences)(No.2024RCKY028)。
文摘Mercury ions(Hg^(2+))and bacteria are widely spread in water pollution and pose a great threat to human health and the environment.Herein,a multifunctional COF Dmta Tph with significant Hg^(2+)adsorption capability and continuous sunlight-driven sterilization property is designed and synthesized by introducing thioether and photosensitive porphyrin in a single molecule.The obtained COF displays a high Hg^(2+)adsorption capacity of 657.9 mg/g at 298 K and a superior antibacterial effect toward Escherichia coli and Staphylococcus aureus under sunlight irradiation.Mechanistic studies reveal that the strong coordination between S species and Hg^(2+)is the main driving force for high Hg^(2+)adsorption capability.The sterilization mechanism clarifies that the inactivation of bacteria is caused by1O_(2)produced from Dmta Tph with the assistance of light irradiation.Noteworthy,when Dmta Tph is applied in the treatment of wastewater,it displays high Hg^(2+)removal efficiency and remarkable antibacterial effect under complex conditions.This study has demonstrated a promising strategy for designing multifunctional COF-based materials,offering great potential in tackling the problem of heavy metal ions and bacteria pollution in water.
基金supported by the National Natural Science Foundation of China(Grant Nos.42272008 and 41972002).
文摘The origins of peloidal micrites in reefal limestone are not yet well understood.Moscovian microbial reefs with abundant peloidal micrites from Guizhou,South China,provide an opportunity to study the peloids and their geological significance for this time interval.Three types of peloids are differentiated:microbial,lithic,and bioclastic peloids.Microbial peloids that are well-sorted and may form in situ by microbial activities.The poorly sorted lithic peloids are derived from erosion and redeposition of the micrite matrix caused by the bottom turbulence induced by periodic storms.Bioclastic peloids are completely micritized fragments of hard parts and shells.Microbial boring and encrustations promote the processes of micritization.Microbial peloids commonly develop in zones with low or normal energy levels,and contribute to the construction and stabilization of the framework.In contrast,the occurrence of lithic peloids reflects that the reefs are destroyed by bottom turbulence during growth.It is suggested that the microbial reefs were deposited under a dynamic balance between constructional versus destructive processes.By comparative analysis,the peloids as microbial in origin play a key role in the growth and stabilization of bioconstructions during Carboniferous,which should be paid more attention in the studies of Carboniferous buildups.
