Single-atom catalysts(SACs)have demonstrated excellent performance in heterogeneous catalytic reactions owing to their maximized atomic efficiency,distinctive geometric,and electronic configurations.However,the effica...Single-atom catalysts(SACs)have demonstrated excellent performance in heterogeneous catalytic reactions owing to their maximized atomic efficiency,distinctive geometric,and electronic configurations.However,the efficacy of SACs remains limited for certain reactions requiring simultaneous activation of multiple reactants over metallic active sites.Herein,we report an atomically dispersed Pt1Ru1 dual-atom pair site anchored on nanodiamond@graphene(ND@G)for CO oxidation.The Pt1Ru1 dual-atom catalyst shows an exceptional turnover frequency(TOF)of 17.6.10^(-2)s^(-1)at significantly lower temperature(30℃),achieving a tenfold increase in TOF compared to singleatom Pt1/ND@G catalyst(1.5.10^(-2)s^(-1))and surpassing to previously reported Pt-based catalysts under similar conditions.Moreover,the catalyst demonstrates excellent stability,maintaining its activity for 40 h at 80℃without significant deactivation.The superior catalytic performance of Pt-Ru dual-atom catalysts is attributed to the synergistic effect between Pt and Ru atoms with enhanced metallicity for improving simultaneous adsorption and activation of CO and O_(2),and the tuning of conventional competitive reactant adsorption into a non-competitive pathway over dual-atom pair sites.The present work manifests the advantages of dual-atom pair sites in heterogeneous catalysis and paves the way for precise design of catalysts at the atomic scale.展开更多
Ultra-dense networks （UDNs） are expected to be applied for the fifth generation wireless system （5G） to meet the requirements of very high throughput density and connections of a massive number of users. Consideri...Ultra-dense networks （UDNs） are expected to be applied for the fifth generation wireless system （5G） to meet the requirements of very high throughput density and connections of a massive number of users. Considering the large amount of small base stations （SBSs）, how to choose proper backhaul links is an important problem under investigation. In this paper, we propose a wireless backhaul algorithm to find an effective backhaul method for densely-deployed SBSs and to maximize energy efficiency of the system. We put forward adaptive backhaul methods of indirect and direct modes. The SBS can select the direct baekhaul which con- nects to the macro base station （MBS） directly, or the indirect backhaul which selects an idle SBS as a relay based on the backhaul channel condition. The algorithm also allocates network resources, including the power of SBSs and system bandwidth, to solve the serious interference problem in UDN. Finally, the simulation results show that the proposed wireless backhaul algorithm has desired performance to achieve higher energy efficiency with required data rate.展开更多
基金supported by the National Key R&D Program of China(2021YFA1502802)the National Natural Science Foundation of China(U21B2092,22202213,22402210,22502215,22502214,22572200,and 22579171)+4 种基金the International Partnership Program of Chinese Academy of Sciences(172GJHZ2022028MI)the Shenyang Bureau of Science and Technology(24-213-3-25)the Natural Science Foundation of Liaoning Province(2025BS0153)Zhongke Technology Achievement Transfer and Transformation Center of Henan Province 2025119The XAS experiments were conducted in Beijing Synchrotron Radiation Facility(BSRF)and Shanghai Synchrotron Radiation Facility(SSRF).
文摘Single-atom catalysts(SACs)have demonstrated excellent performance in heterogeneous catalytic reactions owing to their maximized atomic efficiency,distinctive geometric,and electronic configurations.However,the efficacy of SACs remains limited for certain reactions requiring simultaneous activation of multiple reactants over metallic active sites.Herein,we report an atomically dispersed Pt1Ru1 dual-atom pair site anchored on nanodiamond@graphene(ND@G)for CO oxidation.The Pt1Ru1 dual-atom catalyst shows an exceptional turnover frequency(TOF)of 17.6.10^(-2)s^(-1)at significantly lower temperature(30℃),achieving a tenfold increase in TOF compared to singleatom Pt1/ND@G catalyst(1.5.10^(-2)s^(-1))and surpassing to previously reported Pt-based catalysts under similar conditions.Moreover,the catalyst demonstrates excellent stability,maintaining its activity for 40 h at 80℃without significant deactivation.The superior catalytic performance of Pt-Ru dual-atom catalysts is attributed to the synergistic effect between Pt and Ru atoms with enhanced metallicity for improving simultaneous adsorption and activation of CO and O_(2),and the tuning of conventional competitive reactant adsorption into a non-competitive pathway over dual-atom pair sites.The present work manifests the advantages of dual-atom pair sites in heterogeneous catalysis and paves the way for precise design of catalysts at the atomic scale.
基金jointly supported by the National Natural Science Foundation of China under Grant Nos.61771070 and 61671088the National Science and Technology Major Project under Grant No.2016ZX03001017
文摘Ultra-dense networks （UDNs） are expected to be applied for the fifth generation wireless system （5G） to meet the requirements of very high throughput density and connections of a massive number of users. Considering the large amount of small base stations （SBSs）, how to choose proper backhaul links is an important problem under investigation. In this paper, we propose a wireless backhaul algorithm to find an effective backhaul method for densely-deployed SBSs and to maximize energy efficiency of the system. We put forward adaptive backhaul methods of indirect and direct modes. The SBS can select the direct baekhaul which con- nects to the macro base station （MBS） directly, or the indirect backhaul which selects an idle SBS as a relay based on the backhaul channel condition. The algorithm also allocates network resources, including the power of SBSs and system bandwidth, to solve the serious interference problem in UDN. Finally, the simulation results show that the proposed wireless backhaul algorithm has desired performance to achieve higher energy efficiency with required data rate.
