摘要
在丝光沸石分子筛催化下,β-蒎烯水合反应得到α-松油醇、β-松油醇、1,8-桉叶素、龙脑和异龙脑五种水合产物以及以莰烯和苧烯为主的十种异构化产物。本文主要研究了反应温度、催化剂用量和溶剂介质对产物分布的影响,并对反应机理进行了讨论。
In the presence of mordenite catalyst, hydration of β-pincne resulted
In five hydration products-a-terpineol, l, β-terpineol, l,8-cineol,n-borneol and iso-borneol, and ten isomerization products in which camphene and limonene predominate. The influence of reaction temperature, amount of catalyst and solvent medium on product distribution was studied emphatically, and the reaction mechanism was also studied.
出处
《林产化学与工业》
EI
CAS
CSCD
北大核心
1989年第2期35-41,共7页
Chemistry and Industry of Forest Products
基金
国家自然科学基金项目
