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硼碳氮纳米管的溶剂热法制备及其表征 被引量：6

Solvothermal Preparation and Characterization of B-C-N Nanotubes
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摘要 以无水CH3CN·BCl3和Li3N为原料,以苯为溶剂,在温度为330℃,压力为8～9MPa条件下,利用溶剂热合成方法成功地制备出了BCN三元化合物。X射线粉末衍射(XRD)分析表明,产物为类石墨态结构,透射电子显微镜(TEM)观测到产物中含有B C N纳米管。X射线能谱(XPS)和Fourier变换红外光谱(FTIR)分析表明硼碳氮是以原子级化合的形式存在。 A solvothermal reaction of anhydrous CH_3CN·BCl_3 and Li_3N using benzene as the solvent was carried out to prepare ternary boron carbonitride successfully at 330℃ and 8-9MPa. The analysis of X-ray diffraction pattern indicated that the products have a graphite-like structure. B-C-N nanotubes were observed in the products by transmission electron microscopy. X-ray photoelectron spectroscopy and Fourier transformation infrared spectra were used to confirm their chemical composition and atomic-level hybrid composed of B, C and N atoms.
作者 黄福林 曹传宝 翟华嶂 邱海林 朱鹤孙
机构地区 北京理工大学材料科学研究中心
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2004年第2期168-172,共5页 Journal of Synthetic Crystals
基金 国家自然科学基金资助项目(20171007) 教育部博士点基金项目(1999000718)
关键词 硼碳氮纳米管 溶剂热法 制备方法 X射线能谱 Fourier变换红外光谱 表征技术 材料科学 boron carbonitride solvothermal synthesis XPS FTIR
分类号 TQ127.12 [化学工程—无机化工] TB383 [一般工业技术—材料科学与工程]
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参考文献27

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人工晶体学报
2004年 第2期

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