摘要
本文首次研究了以β二酮及酯作为配体的六种过渡金属配合物的热稳定性,并用DTA-TG和TG-DTG技术研究了配合物的热分解机理,根据分解热估算出配合物的断裂键能。
This paper investigated the thermal stability of Ti, Zr, Sn coordination compounds with β-diketones and esters as ligands, elicited the decomposition mechanism of tbe coordination compounds with DTA-TG, TG-DTG techniques,obtained the bond dissociation energy by simple calculation.
出处
《中国科学院研究生院学报》
CAS
CSCD
1992年第4期373-378,共6页
Journal of the Graduate School of the Chinese Academy of Sciences
关键词
钛
锆
锡
Β二酮
络合物
热化学
Titanium, Zirconium, Tin,thermochemistry, coordination compounds, DTA-TG,TG-DTG