摘要
本文研究了以β二酮及酯作为配体的七种过渡金属配合物:Ti(acac)_2Cl_2、Ti(bzac)_2Cl_2、Tj(bzbz)_2Cl_2、Ti(etac)_2Cl_2、Ti(mesa)_2Cl_2、Sn(bzac)_2Cl_2及Zr(bzac)_2Cl_2的顺磁共振光谱,并将特征配合物Tj(bzac)_2Cl_2、Ti(bzbz)_2Cl_2的ESR谱值参数与其IR吸收峰及MS的特征碎片峰进行了比较。
This paper studied the ESR behaviors of Ti, Zr, Sn Coordination Compounds with β-diketones and esters as ligands, compared the ESR values of the coordination compounds (Ti(bzac)_2Cl_2 and Ti(bzbz)_2Cl_2) with their IR absorptions and special fragment in MS spectrography.
出处
《中国科学院研究生院学报》
CAS
CSCD
1992年第3期277-281,共5页
Journal of the Graduate School of the Chinese Academy of Sciences
关键词
钛
锆
锡
Β二酮
配合物
荷移
ESR
Titanium, Zirconium, Tin, β-diketone, ESR, charge transfer, coordination compounds
