摘要
通过用莫尔斯提出的双原子分子势函数,求解双原子分子振动的薛定谔方程,讨论了双原子分子振动光谱.结果表明,莫尔斯势包含双原子分子振动的一级非谐性质,它能够较好地反映双原子分子振动情况.得出了离解能与振动光谱常数之间的关系.
Through using potential function of diatomic molecules put forward by P.M.Morse and solving Shrdinger vibrating equation of diatomic molecules,discuss vibrating spectrum of diatomic molecules.The result shows that P.M.Morse's potential function includes the first non-harmonic term of vibration of diatomic molecule and well reflects the situation of vibration of diatomic molecules.It concludes the relationship of energy of dissociation and vibrating spectral constant.
出处
《东北师大学报(自然科学版)》
CAS
CSCD
北大核心
2004年第1期50-54,共5页
Journal of Northeast Normal University(Natural Science Edition)
基金
吉林省科技发展计划项目(20020615)
关键词
分子势函数
非谐性
莫尔斯势
离解能
potential function of molecule
non-harmonic
P.M.Morse' potential function
energy of dissociation