摘要
本文合成了14个含氮杂环三烃基锡衍生物,红外光谱,核磁共振谱和质谱的研究表明三烃基锡-1,2,4-三氮唑为以氮原子作桥联的五配位聚合结构化合物,化合物的生物活性和生物选择性主要取决于锡原子上的三烃基。
Fourteen trialkyltin derivatives containing azotic heterocyelie compounds were synthesized. The IR, ~1H, ^(119)Sn and ^(29)Si NMR, MS and elemental analysis were carried out. The results showed that trialkyltin-1,2,4-triazole is an organotin polymer containing fivecoordinated tin atom with bridging nitrogen atoms. The bioassay results showed that the biological effects of the compounds are mainly determined by the trialkyl groups linked with the tin atoms.
出处
《应用化学》
CAS
CSCD
北大核心
1992年第6期52-56,共5页
Chinese Journal of Applied Chemistry
基金
天津市科学基金
关键词
有机锡化合物
氮杂环化合物
organo-tin compound, azotic heterocyclic compound, biological activity, synthesis, acaricide, pesticide