摘要
在室温下,研究了聚醋酸乙烯酯(PVA_c)与NaSCN,聚醋酸乙烯酯——乙烯共聚物(EVA)与NaSCN在摩尔比分别为2∶1,1∶1,0.5∶1的络合物膜,及聚环氧氯丙烷(PECH)和NaSCN,在金属∶氧原子(M∶O)摩尔比为1∶1,1∶4,1∶8的络合物膜的导电性能。在不同温度时,对环氧氯丙烷——环氧乙烷共聚物(PECH-PEO)与LiClO_4,环氧氯丙烷-环氧乙烷-环氧丙烷共聚物(PECH-PEO-PPO)与LiClO_4的M∶O,分别为1∶2,1∶4,1∶8,1∶10,1∶12的络合物膜的导电性能进行了研究。并对PECH-PEO,PECH-PEO-PPO与LiClO_4络合体系进行了红外光谱分析。
The complex of various molar ratio of PV Ac-NaSCN, EVA-NaSCN , PECH-NaSCN, PECH-PEO-LiCIO4, PECH-PEO-PPO-LiClO4 have been prepared. Electrical conductivities of PVAc-NaSCN, EVA-NaSCN , PECH-NaSCN , have been determined at room temperature. Electrical conductivities of PECH-PEO-LiClO4,PECH-PEO-PPO-LiClO4 have been determined at different temperature. Infrared studies have been carried out on PECH-PEO-LiClO4 ,PECH-PEO-PPO-LiClO4
出处
《烟台大学学报（自然科学与工程版）》
CAS
1992年第3期22-28,共7页
Journal of Yantai University(Natural Science and Engineering Edition)
关键词
聚合物
电学性能
固体电解质
Polymer complex with sodium ion. Polymer complex with lithium ion. Electrical property. Solid state ionics. Superionic conductor.
