摘要
本文对现有中,高温固相化学反应方法合成含硫原子簇化合物作了探讨,介绍了我们实验室用低热温度固相反应合成原子簇化合物的新方法,总结了几年来我们用此法合成的S-Mo(W)-Cu(Ag)原了簇化合物,并测定结构二十余个,其中包括了含有二十个金属原子的大核原子簇化合物[(n-Bu)_4N]_4[Mo_8Cu_(12)S_(32)]。
<abstract>In this paper。 weintroduce a new method of synthesis of cluster compounds by solid state reactions at
low heating tempcraturc, and summarizc Mo(W)一Cu(Ag)～S cluster compounds, we have recently Ob
tained using this method and structurally characterize about twenty of new cluster compounds by X—ray
single crystal analysis,including the bigger mixed cluster compound[(n-Bu)_4N_4][Mo_8Cu_12S_32].
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1992年第4期472-480,共9页
Chinese Journal of Inorganic Chemistry
