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电生羟基自由基降解有机染料的研究 被引量:1

Study on Electro-Generated Hydroxyl Radical Using in Degradation of Dyes
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摘要 以Pb/PbO_2为工作电极以CoSO_4为催化剂,利用电生羟基自由基对中性红、罗丹明B、碱性品红等3种有机染料进行了降解。并且研究了电解电位、 pH值、温度等因素对染料降解脱色的影响。结果表明,脱色率接近100%,COD去除率达90%以上。实验证明反应符合一级反应动力学模式,实验还测定了动力学参数。 Electro-generated hydroxyl radical was used to degrade neutral red, rhodamine B and alkaline fuch sine with Pb/PbO2 as electrode and CoSO4 as ca -talysis. The affected factors of electrolysis potential, pH value, temperature etc. in dyes'degrading and decolorizing have been studied. The results showed that the decolorizing rate was near 100% and COD removal rate was above 90%. The experiments proved that the reaction according with grade I reactive kinetic mode, and kinetic parameters were also determined.
出处 《上海环境科学》 CAS CSSCI CSCD 北大核心 2003年第12期888-891,共4页 Shanghai Environmental Sciences
关键词 电生羟基自由基 降解 有机染料 脱色 影响因素 动力学参数 废水处理 Electro-generated hydroxyl radical Organic dye Degradation Decolorization Affected factor Kinetic parameters
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  • 1T. Tzedakis,A. Savall,M. J. Clifton. The electrochemical regeneration of Fenton’s reagent in the hydroxylation of aromatic substrates: batch and continuous processes[J] 1989,Journal of Applied Electrochemistry(6):911~921
  • 2李安祥,张本才,李宝林.邻硝基苯甲醛生产方法评介[J].现代化工,1992,12(4):49-50. 被引量:6

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  • 1王敏,朱志远,杨睿媛,王文锋,边绍伟,沈忠群,顾建忠,吴明红.电子束辐照处理水溶液中的活性染料[J].核技术,2005,28(1):40-45. 被引量:20
  • 2Gao J Z.Pakistan J Biolog Sci[J],2005,9(2):323
  • 3Gai K,Dong Y J.Plasma Sour Sci Tech[J],2005,14:589
  • 4Alam M S,Kelm M,Rao B S M,Janata E.Rad Phys Chem[J],2004,71:1 087
  • 5Hu Z A,Wang X Y,Gao J Z.Plasma Sci Technol[J],2001,5:927
  • 6Ohgiyama M T,Clements J S.IEEE Trans Ind Appl[J],1996,32(1):106
  • 7Sengupta S K,Sign Om Prakash.J Electoanal Chem[J],1994,369:113
  • 8Tezuka M,Iwasaki M.Plasma Ions[J],1999,1:23
  • 9Tezuka M,Iwasaki M.Thin Solid Films[J],1998,316:123
  • 10Tezuka M,Iwasaki M.Thin Solid Films[J],2001,386:204

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