摘要
水杨醛与邻苯二胺以2∶1摩尔比在无水乙醇中反应,合成了水杨醛缩邻苯二胺Schiff碱,利用该配体与Cu(Ⅱ)、Zn(Ⅱ)、Ni(Ⅱ)和Co(Ⅱ)金属离子络合,合成了四个新型的Schiff碱配合物,其结构用红外光谱(KBr压片)及紫外可见分光光谱进行了表征,并研究了配合物对H2O2氧化Vc的催化活性.
The Schiff-base salicylaldehyde-1,2-phenylendiamine and its metal complexes was synthesized by salicylaldehye acid 1,2-phenylendianmine and Cu(Ⅱ) 、Zn(Ⅱ) 、 Ni(Ⅱ) 、 Co(Ⅱ) . The structures of the complexes was characterized by IR and Uv-vis . Catalytic oxidation activity of its complexes was determined in H2O2-Vc system.
出处
《西华师范大学学报（自然科学版）》
2003年第4期423-425,共3页
Journal of China West Normal University(Natural Sciences)
