摘要
采用简便易行的方法合成了4种卟啉化合物:四苯基卟啉(TPP)、Meso 四(对磺酸基苯基)卟啉(TPPS4)、Meso 四(对羟基苯基)卟啉[T(OH)4PP]和Meso 四(对甲氧基苯基)卟啉[T(OCH3)PP]。可见光谱分析表明苯环上对位取代基的引入和溶剂的极性可使光谱发生不同程度的蓝移或红移,这对改善卟啉化合物的光吸收性能有着重要的指导意义。
Four kinds of porphyrin compounds have been synthesized by simple method, which involve tetraphenylporphyrin (TPP), meso-tetrashydroxyl phenyl porphyrin (TPPS_4), meso-tetrahydroxylphenyl porphyrin , and meso-tetramethoxyphenyl porphyrin . Analysis of visible spectrum shows that the substitutance on benzene ring and polarity of solvent make their spectrum move toward blue or red, which is of importance to improve porphyrin compounds' photoabsorption performance.
出处
《化工科技》
CAS
2003年第5期15-17,共3页
Science & Technology in Chemical Industry
基金
辽宁省教育厅基金项目(202223203)。
