摘要
A novel porous coordination polymer [La(C8H6NO2)3]n was synthesized by hydrothermal reaction of flexible ligands 3 (3 pyridyl)acrylate and La(NO3)3· 6H2O. The structure was characterized by elemental analysis, IR spectroscopy and X ray single crystal diffraction. X ray single crystal analysis reveals the structure consists of [La(C8H6NO2)3]n. It crystallizes in monoclinic crystal system with space group P2(1)/c. Crystallographic date: a=0. 7889(3)nm, b=2.5916(9)nm, c=1.1489(4)nm, α =90.00° , β =95.219(6)° , γ =90.00° , V=2.3393(15)nm3, Z=4, Dc=1.656g· cm- 3, μ =1.871mm- 1, F(000)=1152, R1=0.0328, wR2=0.0522. CCDC: 211700.
A novel porous coordination polymer [La(C8H6NO2)(3)](n) was synthesized by hydrothermal reaction of flexible ligands 3-(3-pyridyl) acrylate and La(NO3)(3) (.) 6H(2)O. The structure was characterized by elemental analysis, IR spectroscopy and X-ray single crystal diffraction. X-ray single crystal analysis reveals the structure consists of [La(C8H6NO2)(3)](n). It crystallizes in monoclinic crystal system with space group P2(1)/c. Crystallographic date: a = 0.7889 (3) nm, b = 2.5916 (9) nm, c = 1.1489 (4) nm, alpha = 90.00degrees, beta = 95.219(6)degrees, gamma = 90.00degrees, V = 2.3393 (15) nm(3), Z = 4, D-c = 1.656g (.) cm(-3), mu = 1.871 mm(-1), F (000) = 1152, R-1 = 0.0328, wR(2) = 0.0522.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2003年第11期1245-1248,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20176008)。
