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Calculating model of mass action concentrations for Ag-Au-Cu melts 被引量:5

Calculating model of mass action concentrations for Ag-Au-Cu melts
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摘要 Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent research work, Showing that the model formulatedcan reflect the structural characteristics of these melts. In thismodel, without the help Of any empirical parameters, only threeequilibrium constants are used, hence it is simple, lear, andfavorable to the sim- Plification of calculation. Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent research work, Showing that the model formulatedcan reflect the structural characteristics of these melts. In thismodel, without the help Of any empirical parameters, only threeequilibrium constants are used, hence it is simple, lear, andfavorable to the sim- Plification of calculation.
出处 《Rare Metals》 SCIE EI CAS CSCD 2002年第1期43-47,共5页 稀有金属(英文版)
关键词 ACTIVITY mass action concentration EUTECTIC Solid solution activity mass action concentration eutectic Solid solution
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参考文献6

  • 1Gallois B. and Lupis C H.P., Surface tensions of liquid Ag-Au-Cu alloys [J], Metall. Trans. B, 1981.12B (4): 679.
  • 2Hajra J.P., Hong-Kee Lee, and Frohberg M.G., Representation of thermodynamic properties ofternary systems and its application to system Ag-Au-Cu ar1350 K [J], Met. Trans. B, 1992, 23B (6): 747.
  • 3Baker H., Okamoto H., Henry S.D., Davidson G.M,Fleming M.A., Kacprzak L., Lampman H. F., and Scott W.W., ASM Handbook Vol. 3, Alloy Phase Di agrams [M], The Materials Information Society, Materials Park, Ohio 44073-0002, 1992: 2.25, 2.28,2.68
  • 4Hultgren R., Desai P.D., Hawkins D.T., et al., Selec ted Values of the Thermodynamic Properties of Bi nary Alloys [M], American Society for Metals, Metals Park, Ohio 44073, 1973: 29-30, 267-269.
  • 5Zhang J., Calculating Thermodynamics of Metallurgical Melts (in Chinese) [M], The Metallurgica;Industry Press, Beijing, 1998:91-113.
  • 6Subramanian P.R. and Perepezko J.H., The Ag-Cu system [J], Journal ofPhase Equilibria, 1993, 14(l): 62.

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