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液体三氧化硫的工业化生产 被引量:3

Industrial Production of Liquid Sulphur Trioxide
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摘要 含20%游离SO_3的发烟硫酸通过加热蒸发,产生SO_3气体和含15%游离SO_3的发烟硫酸。SO_3气体送去精馏、冷凝,制得纯净的液体SO_3;含15%游离SO_3的发烟硫酸返回制酸系统。为了改善液体SO_3的稳定性,在产品中加入了特制的稳定药剂。设计了专门的加药装置和取样装置,以确保系统的密闭、安全。整个系统都设有伴热或保温。 The oleum containing 20% free SO3 is heated to generate SO3 gas, which is purified by distillation and condensation to obtain pure liquid SOs product. The remaining oleum -with 15% free SO3 concentration is recycle to the H2SO4 system. A special stabilizer is added into the liquid SO3 to improve its stability. For the sealing and safety of the plant, a special stabilizer-filler and a sampling means are designed. The whole plant is installed with supplementary heating or thermal insulation,
作者 李琳 王树兰
机构地区 吉化公司染料厂
出处 《硫酸工业》 CAS 1992年第2期51-54,63,共4页 Sulphuric Acid Industry
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同被引文献17

  • 1康文斌.液体三氧化硫泵泄漏原因分析及对策[J].硫酸工业,2004(4):32-34. 被引量:2
  • 2陈瑶,曾崇余.环己酮缩合制备2-(1-环己烯基)环己酮的研究[J].精细石油化工,2005,22(4):4-7. 被引量:4
  • 3陈华.液体三氧化硫的生产工艺[J].硫磷设计与粉体工程,2006(2):30-33. 被引量:2
  • 4LI Xing-hai, YANG Xin-ling, LIANG Xiao-mei, et al. Synthesis and Biological Activities of 2-Oxocycloalkylsulfonamides[J]. Bioorganic & Medicinal Chemistry, 2008, 16(8): 4538-4544.
  • 5LI Xing-hai, WU De-cai, QI Zhi-qiu, et al. Synthesis, Fungicidal Activity, and Structure-activity Relationship of 2-Oxo and 2-Hyd roxycycloalkylsulfonamides[J]. Journal of Agricultural and Food Chemistry, 2010, 58(21): 11384-11389.
  • 6LI Xing-hai, YANG Xin-ling, LING Yun, et al. The Synthesis and Fungicidal Activity of Novel-oxocycloalkylsulfonylureas[J]. Journal of Agricultural and Food Chemistry, 2005, 53: 2202-2206.
  • 7Sulfur Trioxide. Http://en.wikipedia.org/wiki/Sulfur_trioxide.
  • 8Preparation of Sulfur Trioxide and Oleum, by GARAGE CHEMIST. Http://www.sciencemadness.org/member_ publications/SO3 and oleum.pdf.
  • 9Sulfur Trioxide from Sodium Hydrogen Sulfate. Http://www. sciencemadness.org/talk/viewthread.php?tid= 10217.
  • 10王道全,汪晓平.三氧化硫·二氧六环加合物的制备与反应活性的研究[J].化学试剂,1997,19(1):37-39. 被引量:2

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