摘要
测定了球碳C60/C70及其衍生物C60Xn/C70Xn的加氢汽油溶液分别与环烷酸钴[Co(naph)2]反应的紫外可见吸收光谱及C60Xn与Co(naph)2反应沉淀物的红外吸收光谱。结果表明:C60/C70及其衍生物均可与Co2+发生配位反应,形成π配体络合物,讨论了可能的反应机理。
Fullerences(C60/C70) and it's derivatives(C60Xn/C70Xn) could react which Co(naph)2 respectively in hydrogenated gasoline solution, the reaction mixtures were analyzed by UVvis spectroscopy, and the IR spectroscopy of the reaction sediment was carred out simultaneously.The resuts showed that C60/C70 or it's derivatives were complexed with Co2+, and forming π complex compounds, the reaction mechanism was discussed.
出处
《应用化工》
CAS
CSCD
2003年第3期6-8,15,共4页
Applied Chemical Industry
基金
国家自然科学基金资助项目(29674016)
