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掺杂LaNiO_3型双功能氧电极的电化学性能 被引量：3

Study on electrochemical properties of doped LaNiO_3 perovskite bifunctional oxygen electrodes
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摘要 双功能氧电极由于在再生燃料电池和可充金属 空气电池中具有重要应用,因此是人们的研究热点。LaNiO3是钙钛型复合氧化物中唯一的金属型化合物,A位掺杂会造成晶格上有序化的氧空位增多,使电极性能下降,所以对于LaNiO3的掺杂改性研究很少。我们采用溶胶 凝胶法制备了一系列LaNi1-yCoyO3(y=0.0～1.0)型的B位掺杂的LaNiO3钙钛矿催化剂,并以活性炭为载体制备双功能氧电极。对催化剂进行了XRD结构分析,结果表明均为钙钛矿单相。采用三电极体系测试了氧电极的阴极极化和阳极极化的稳态极化曲线和循环伏安曲线。结果表明,B位掺杂可显著提高LaNiO3催化剂的电催化性能,其中LaNi0.8Co0.2O3的双功能电催化活性最好。 A series of LaNi1-yCoyO3(y=0.0-1.0) perovskite catalysts used as the catalysts of bifunctional oxygen electrodes were prepared by solgel method. The samples were characterized by XRD. Their electrocatalytic activity at oxygen electrodes were investigated by steady polarization curves and cyclic voltammetry method. The results show that the electrocatalystic properties of LaNiO3 is improved by doping the B ions and the LaNi0.8Co0.2O3 used as electrocatalyst of bifunctional oxygen electrode has excellent catalytic activity and stability on both oxygen reduction reaction and oxygen evolution reactions.
作者 宋世栋 唐致远 刘建华 于瑞林 潘丽珠
机构地区 天津大学化工学院应用化学系
出处 《电源技术》 CAS CSCD 北大核心 2003年第B05期154-156,共3页 Chinese Journal of Power Sources
关键词 双功能氧电极 电化学性能 燃料电池 金属-空气电池 掺杂 LANIO3 bifunctional oxygen electrode metal-air battery perovskite composite oxide fuel cell
分类号 TM911.41 [电气工程—电力电子与电力传动]
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参考文献5

  • 1王鹏,姚立广,王明贤,吴维.La_(1-x)Sr_xCoO_(3-δ)氧化物电极的电子结构[J].材料研究学报,2000,14(1):92-95. 被引量：4
  • 2M ueLEER S, HAAS O, SCHLATTER C, et al. Development of a 100 W rechargeable bipolar zinc/oxygen battery [J ]. J Appl Electrochem, 1998, 28:305.
  • 3CHARTOUNI D, KURIYAMA N, KIYOBAYASHI T, et al. Airmetal hydride secondary battery with long cycle life[J]. J Alloys and Compounds, 2002,330:766.
  • 4HERMANN V, DUTRIAT D, M ueLLER S, et al. Mechanistic studies of oxygen reduction at La0.6Ca0.4CoO3-activited carbon electrodes in a channel flow cell[J]. Electrochim Aeta, 2000,46:365.
  • 5SINGH R N, LAL B. High surface area lanthanmn cobaltate and it's A and B sites substituted derivatives for electrocatalysis of O2 evolution in alkaline solution[J]. Int J Hydrogen Energy, 2002, 27:45---55.

二级参考文献1

  • 1Li G，J Solid State Chem，1990年，89卷，167页

共引文献3

同被引文献38

  • 1杨裕生,王维坤,苑克国,曹高萍,王安邦.锂电池正极材料有机多硫化物的展望[J].电池,2002,32(z1):1-5. 被引量：42
  • 2宋世栋,唐致远,潘丽珠,南俊民.掺杂LaNiO_3型双功能氧电极的研究——溶胶-凝胶制备方法[J].天津大学学报（自然科学与工程技术版）,2005,38(9):774-779. 被引量：4
  • 3WEI Z, HUANG W, ZHANG S, et al. Induced effect of Mn3O4 on formation of MnO2 crystals favourable to catalysis of oxygen reduction[J]. J Appl Electronchem,2000,30(10): 1 133-1 136.
  • 4LINDEN D. Handbook of Batteries[M]. McGraw-Hill, New York,2002.38-45.
  • 5HASVOLD Q, HENRIKSEN H, MELVAR E, et al. Sea-water battery for subsea control systems[J]. J Power Sources, 1997, 65(1-2):253-261.
  • 6MAO L, ZHANG D, SOTOMURA T,et al. Mechanistic study of the reduction of oxygen in air electrode with manganese oxides as electrocatalysts[J]. Electrochimica Acta,2003,48(8): 1 015- 1021.
  • 7OHSAKA T, MAO L, ARIHARA K, et al .Bifunctional catalytic activity of manganese oxide toward O2 reduction:novel insight into the mechanism of alkaline air electrode [J].Electrochem. Commun,2004,6(3):273-277.
  • 8CAO Y, YANG H, AI X, et al. The mechanism of oxygen reduction on MnO2-catalyzed air cathode in alkaline solution [J].J Electroanal Chem,2003,557:127- 134.
  • 9YANG J, XU J. Nanoporous amorphous manganese oxide as electrocatalyst for oxygen reduction in alkaline solutions [J].Electrochem Comun,2003,5(4):306-311.
  • 10ZHANG G, ZHANG X. MnO2/MCMB electrocatalyst for all solidstste alkaline zinc-air cells [J].Elecchimica Acta,2004,49 (6):873-877.

引证文献3

二级引证文献21

电源技术
2003年 第B05期

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