摘要
按配体类型介绍了近十几年来几种新型Ni(Ⅱ)、Pd(Ⅱ)催化剂的组成、结构、合成方法及其在烯烃与极性单体共聚中的应用和发展状况,同时对它们的聚合机理和影响因素进行了讨论。
Various novel Ni(II) and Pd(II) catalysts for the copolymerization of olefins with polar monomers in the passing decade were introduced.Their composition,structure,synthesis and their application in copolymerization were reviewed according to their different ligands.Mechanism and influencing factors of the polymerization were also discussed.
出处
《石油化工》
CAS
CSCD
北大核心
2003年第5期438-442,共5页
Petrochemical Technology
关键词
烯烃
极性单体
共聚合
镍
钯
金属催化剂
研究进展
olefins
polar monomer
copolymerization
nickel catalysts
palladium catalysts