期刊文献+

用高锰酸钠氧化法去除水中的苯胺 被引量:8

Eliminating Aniline in Water by Sodium Permanganate Oxidation
在线阅读 下载PDF
导出
摘要 研究了高锰酸钠对水中苯胺的去除作用·实验结果表明,随着高锰酸钠投加量的增加,水中苯胺的去除率增加,在苯胺初始质量浓度为10mg/L,温度为18℃,pH值为6 8,反应时间为30min的条件下,高锰酸钠质量浓度为30mg/L时,苯胺的去除率达92 12%·水样的pH值对苯胺去除效果有较大影响,在强酸性及强碱性条件下苯胺去除效果高于中性条件,pH值为3时,苯胺去除率为97 55%;pH值为11时,苯胺去除率为96 33%·升高温度或延长反应时间对苯胺的去除均有正的影响·苯胺是通过高锰酸根和新生态的氧将其氧化成苯醌而去除的· ?Eliminating aniline in water was investigated by sodium permanganate. It is showed that with the increase of sodium permanganate, aniline eliminating rate increases. Aniline eliminating rate reaches 9212% by the condition of aniline concentration 10?mg/L, temperature 18?℃,pH 68, reaction time 30 min and sodium permanganate 30?mg/L. The pH value of water sample plays a role on aniline elimination. The effect of removing aniline in alid or alkaline solutions is more significant than in neutral water. The aniline eliminating rate is 9755% at pH value 3 and 9633% at pH value 11. Increasing the temperature or the reaction time has good effects on removing aniline. By the cooperation of permanganate and the formed oxygen, aniline is oxidated into guinone and removed.
出处 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 2003年第5期475-477,共3页 Journal of Northeastern University(Natural Science)
基金 辽宁省自然科学基金资助项目(0022054)
关键词 水处理 高锰酸钠 氧化 苯胺去除率 water treatment sodium permanganate oxidation aniline eliminating rate
  • 相关文献

参考文献10

  • 1王广建,曹长青.用Fe^0-H_2O_2氧化法处理高浓度有机废液研究[J].工业水处理,2001,21(9):21-23. 被引量:8
  • 2冷文华,张昭,成少安,张鉴清,曹楚南.光电催化降解苯胺的研究——单槽与双槽光反应器对比[J].环境科学学报,2002,22(1):40-44. 被引量:14
  • 3Enrigue B. Electrochemical destruction of aniline and 4chloroaniline for wastewater treatment using a carbon-PTEFO2-fed cathode[J]. Electrochem Soc , 1995,142(6) :1733- 1741.
  • 4Kirk D W, Sharifian H. Anodic oxidation of aniline for wastewater treatment[J]. Appl Electrochem, 1995,15(2) :285 - 292.
  • 5Mcclung S M, Lemley T. Electrochemical treatment and HPLC analysis of wastewater containing acid dyes [ J ].Textile Chemist and Colorist, 1994,26(5) : 17 - 22.
  • 6Cloyna E F, Li L, Mcbrayer R N. Engineering aspects of supercritical water oxidation[ J ]. Wat Sci Tech, 1994,3 (9) :1 - 10.
  • 7Banner H E, Huang C Y, Johnson T, et al. Supercritieal water oxidation: an emerging technology [ J ]. Hazard Water, 1992,31 (4) ~ 1 - 17.
  • 8Li R,Thomton T D, Savage P E. Kinetics of CO2 formation from the oxidation of phenols in supercritical water [ J ].Environ Sci Technology, 1992,26(6) :2388 - 2392.
  • 9Gerscher H, Heller A. The role of oxygen in photooxidation of organic molecules on smaiconductor particles[J ]. J Phys Chem, 1991,95(13) :5261 - 5266.
  • 10Richard J W. Mineral-catalyzde Fenton-like oxidation of sorbed chlorobenzenes[J ]. Water Environment Research,1997,69(3) :269 - 275.

二级参考文献3

共引文献19

同被引文献151

引证文献8

二级引证文献37

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部