摘要
在自行设计和安装的一套微反 色谱联用装置上,以TGH为催化剂,进行了二氧化碳对羰基硫催化水解本征动力学影响的研究,得出了在低温50℃～70℃、高水汽摩尔比(H2O COS=60～550),分别对原料气中有无存在CO2的条件下,采用非线性Marquart法对实验数据进行回归,所建立的本征动力学方程式为:1.82×1014exp-75800H2O8.374T×PCOS×P-0.
A microreactorGC apparatus has been used for studying COS hydrolysis reaction kinetics over TGH catalyst The intrinsic reaction kinetics of COS hydrolysis over a TGH catalyst was investigated in the temperature range of 50?℃～70?℃、 H2O/COS molar ratio of 60～550 with the presence of CO2 Nonlinear Marquart Regression was employed to analyze the experimental data The reaction kinetics are expressed as follows:－rCOS＝dxdWFCOS＝1.82×1014exp－75?8008.374T×PCOS×P－0.5H2O1+kCO2×PCO2The kinetic model can be interpreted the reaction in terms of mechanism The presence of CO2 seems not to change rate constant and activation energy of COS hydrolysis reaction
出处
《燃料化学学报》
EI
CAS
CSCD
北大核心
2003年第2期149-155,共7页
Journal of Fuel Chemistry and Technology
