摘要
基于全球对可持续发展的日益关注,以及生物基呋喃类高分子材料表现出的优势特性,呋喃基高分子材料已成为现有石油基高分子体系的重要替代和补充.本文综述了近年来呋喃环单体的高效制备方法及其在功能高分子材料中的应用进展.重点介绍了关键呋喃基材料单体的催化合成路径,包括光、电催化等绿色合成新技术.同时,探讨了这些单体在聚酯、聚酰胺、聚酰亚胺等功能高分子材料中的应用,分析了呋喃基材料在阻隔性、阻燃性、耐热性等方面的独特优势,及其在包装材料、电子电气、新能源等领域的应用潜力,最后指出了当前面临的机遇和挑战.
Based on the global increasing focus on sustainable development,furan-based polymeric materials have exhibited advantageous properties and emerged as significant alternatives and complements to petroleum-based polymer systems.This review summarizes recent advances in efficient preparation methods of furan-ring monomers and their applications in functional polymeric materials.It specifically highlights catalytic conversion pathways for key furan-ring monomers,including environmentally friendly synthesis technologies such as photo-and electro-catalysis.The review investigates the implementation of these monomers in functional polymers,including polyesters,polyamides,and polyimides,while summarizing the distinctive advantages of furan-based materials regarding barrier properties,flame retardancy,and heat resistance.Additionally,this review discusses furan-based materials’potential applications in packaging materials,electronics,new energy sectors,and other fields,along with further opportunities and challenges.
作者
储玉婷
张文艳
李奉城
李世东
王闽
胥李志
李闯
傅尧
Yuting Chu;Wenyan Zhang;Fengcheng Li;Shidong Li;Min Wang;Lizhi Xu;Chuang Li;Yao Fu(Anhui Key Laboratory of Biomass Chemistry,University of Science and Technology of China,Hefei 230026,China;Institute of Advanced Technology,University of Science and Technology of China,Hefei 230031,China)
出处
《中国科学:化学》
北大核心
2025年第9期2808-2827,共20页
SCIENTIA SINICA Chimica
基金
国家自然科学基金(编号:22293011,T2341001)资助项目。
关键词
生物质
平台分子
呋喃基单体
功能材料
材料单体结构设计
biomass
platform molecules
furan-based monomers
functional materials
material monomer structure design
