摘要
根据分子连接方式的不同以及是否为中性分子,将近年来报道合成的高能耐热化合物划分为稠环类、联杂环类和离子型三类。研究综述了三类高能耐热化合物的结构特征、合成方法与物化以及爆轰性能,并对三类高能耐热化合物的应用前景进行评价;展望了高能耐热化合物的合成发展方向:开发普适性的骨架构筑技术、推进计算模拟与分子设计融合、创新绿色高效合成工艺,为设计合成新型高能耐热化合物提供参考借鉴。
According to the connection mode of molecules and whether the molecule is neutral,the high-energy heat-resistant compounds reported in recent years are divided into three categories:fused ring,linked heterocyclic and ionic.The structural characteristics,synthesis methods,physicochemical properties and detonation performances of three kinds of high-energy heat-resistant compounds are reviewed.and the application prospects are evaluated.The development direction of the synthesis of high-energy heat-resistant compound is prospected:developing universal construction technology of skeleton,promoting the integration of computational simulation and molecular design,and innovating green and efficient synthesis process.It provides a reference for the design and synthesis of new high-energy heat-resistant compounds.
作者
付辉
单雨佳
田天
王金鑫
王涛
张文全
FU Hui;SHAN Yu-jia;TIAN Tian;WANG Jin-xin;WANG Tao;ZHANG Wen-quan(China Academy of Engineering Physics,Institute of Chemical Materials,CAEP,Mianyang 621999,China;School of Nuclear Engineering,Rocket Force University of Engineering,Xi′an 710025,China)
出处
《含能材料》
北大核心
2025年第6期658-670,共13页
Chinese Journal of Energetic Materials
基金
陕西省自然科学基金(2024JC-ZDXM-01)。
关键词
高能耐热化合物
合成方法
热稳定性
爆轰性能
high-energy heat-resistant compounds
synthesis method
thermal stability
detonation performance
