摘要
用三氧化铬-丙酮、三氧化铬-乙酸、重铬酸钠-硫酸等氧化剂对异黄樟油素进行了氧化反应.用GC-MS法分析了反应主要产物,确认出了9种氧化产物的结构.用气相色谱法分析了不同条件下原料的转化及各种氧化产物的含量,认为在足量重铬酸钠氧化下,胡椒醛的得率较高.
The oxidation of isosafrole is reaction with chromic anhydride-acetone,chromic anhydride-acetice acid,sodium bichromate-sulfuric acid and so on. Major products have been analysed and the structure of nine products among them identified with GC-MS. It is claimed that the productire rate of piperoncel will get higher in the condition of adequate sodium bichromates.
出处
《江西师范大学学报（自然科学版）》
CAS
2002年第4期356-359,共4页
Journal of Jiangxi Normal University(Natural Science Edition)
基金
国家自然科学基金资助项目(20063001)
