摘要
分别由香茅醇和四氢香叶醇进行溴化反应合成香茅基溴(1-溴-3,7-二甲基-6-辛烯)和四氢香叶基溴(1-溴-3,7-二甲基辛烷)。再以这两种溴代物为原料,分别与二甲胺、二乙胺、二正丙胺、吗啉反应合成得到8种氢化柠檬基叔胺。各化合物都用IR、^(1)H NMR、^(13)C NMR与MS分析方法表征了结构,并对叔胺的质谱分析数据进行了讨论。
Citronelloyl bromide(1-bromo-3,7-dimethyl-6-octene)and tetrahydrogeraniyl bromide(1-bromo-3,7-dimethyl-octane)were synthesized by bromination reaction of citronellol and tetrahydrogeraniol,respectively.Then the two bromides were used as raw materials and reacted with dimethylamine,diethylamine,din-propylamine and morpholine respectively to synthesize 8 kinds of hydrogenated citronyl tert-amines.The structures of all compounds were characterized by IR,^(1)HNMR,^(13)CNMR and MS,and the results of mass spectrometry of tertiary amines were discussed.
作者
彭云
昌家宇
肖转泉
陈尚钘
范国荣
廖圣良
王宗德
PENG Yun;CHANG Jia-yu;XIAO Zhuan-quan;CHEN Shang-xing;FAN Guo-rong;LIAO Sheng-liang;WANG Zong-de(College of Forestry,Jiangxi Agricultural University,East China Woody Fragrance and Flavor Engineering Research Center of National Forestry and Grassland Administration,Camphor Engineering Research Center of NFGA/Jiangxi Province, Nanchang 330045,China;College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027,China)
出处
《化学研究与应用》
CAS
CSCD
北大核心
2021年第11期2234-2239,共6页
Chemical Research and Application
基金
国家重点研发计划课题项目(2017YFD0600704)资助
国家自然科学基金项目(31960295)资助
江西省主要学科学术与技术带头人培养计划项目(20204BCJL23045,20204BCJ22022)资助
江西省研究生创新专项资金项目(YC2020-S235)资助。
关键词
香茅醇
四氢香叶醇
溴代
叔胺
结构分析
citronellol
tetrahydrogeraniol
bromo
tertiary amine
structure analysis
