摘要
为烟用丝束的产品质量安全提供技术支撑,建立烟用丝束中残余丙酮的静态顶空-气相色谱-质谱(SHS-GC-MS)外标定量测定方法。结果表明:最佳检测条件是基质校正剂为三乙酸甘油酯,样品经80℃、20 min静态顶空后,采用TG-624柱,GC-MS/选择离子监测(SIM)模式检测,外标法定量,该条件下,烟用丝束中丙酮的线性关系良好(R^2=0.9998),检出限(LOD)为0.12μg/g,加标回收率为102.22%~120.56%,相对标准偏差RSD<4.13%,该方法灵敏度高、准确性和精密度较好,可用于烟用丝束中残余丙酮的检测。
The static headspace-gas chromatography/mass spectrometry(SHS-GC-MS)external quantity method is established for detecting residual acetone in filter tow to provide the technical support for product quality safety of filter tow.Result:The optimal detection conditions include glyceryl triacetate(matrix correction agent),sample treatment at 80℃ for 20 min,TG-624 column,GC-MS/selective ion monitoring(SIM)mode and external quantity method.The R^2,LOD,recovery and RSD of residual acetone in filter tow detected by SHS-GC-MS under the optimal detection conditions are 0.9998,0.12μg/g,102.22%-120.56% and<4.13% respectively.The static headspace-gas chromatography/mass spectrometry(HS-GC-MS)external quantity method with the advantages of high sensitivity,good accuracy and precision can be used in detection of residual acetone in filter tow.
作者
罗熹
云雪
王加忠
姬厚伟
赖东辉
刘剑
LUO Xi;YUN Xue;WANG Jiazhong;JI Houwei;LAI Donghui;LIU Jian(Technology Center,China Tobacco Guizhou Industrial Co.,Ltd.,Guiyang,Guizhou 550009,China)
出处
《贵州农业科学》
CAS
2019年第12期130-133,共4页
Guizhou Agricultural Sciences
基金
贵州中烟工业有限公司科技项目“滤棒中苯及苯系物残留量顶空-气质检测方法研究及应用”（GZZY/KJ/JS/2017CY011-1）
关键词
烟用丝束
静态顶空-气相色谱-质谱
丙酮
含量
filter tow
static headspace-gas chromatography/mass spectrometry(SHS-GC-MS)
acetone
content
