摘要
介绍了一种新颖的具有C_2对称性的手性双磷杂环戊烷配体DuPHOS,此配体在烯酰胺类、2-烷基琥珀酸类、α-羟基酯类、开链烯醇酯类、酮类等众多类型底物的不对称催化氢化反应中显示出了极高的对映体选择性,本文对此配体的最新研究进展进行了综述。
A new class of electron - rich symmetric 2,4 - disubstituted phosphetanes (DuPHOS) is developed in this paper, DuPHOS is proven to be aversatile and efficient chiral ligand through the asymmetric catalytic hydrogenation conducted by many kinds of substrates.
出处
《化工时刊》
CAS
2002年第10期18-21,共4页
Chemical Industry Times
