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一种新型铜缓蚀剂的缓蚀性能及机理研究 被引量:6

INHIBITIVE PROPERTIES AND MECHANISM OF A NEW INHIBITOR FOR COPPER
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摘要 通过挂片试验、电化学研究及表面分析 ,研究了ET及其与BTA的复合配方ETB在内冷水中对发电机空芯铜导线的缓蚀作用 ,并与BTA的缓蚀性能进行了对比。研究结果表明 ,ET对铜具有较好的缓蚀作用 ,与BTA复配后 ,在铜表面形成致密络合物膜 ,其缓蚀作用比ET及BTA单独使用时都强 。 The inhibitive properties of ET and ETB (mixture of ET and BTA) for copper in domestic water-cooled generators were studied by copper-content measurement, electrochemical polarization and surface analysis. The inhibitive properties of ET and ETB were compared with those of benzotriazole. The results indicated that the inhibitive properties of ET for copper were slightly superior to BTA. Furthermore, ETB was showed to be the most effective one among the inhibitors tested and it hindered anode reaction. The results of XPS showed that ETB inhibited corrosion by forming film on the surface of copper.
出处 《腐蚀与防护》 CAS 2002年第9期387-388,400,共3页 Corrosion & Protection
关键词 新型 铜缓蚀剂 缓蚀性能 机理 研究 复配 协同作用 Copper Inhibition Mix Synergistic action
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参考文献4

  • 1吴荫顺.腐蚀试验方法与防腐蚀检测技术[M].北京:化学工业出版社,1996..
  • 2张大全,周国定,庞学良.聚合物缓蚀剂的研究开发及应用[J].腐蚀与防护,2000,21(7):300-303. 被引量:9
  • 3佚名.火力发电厂水、汽试验方法[M].北京:水利电力出版社,1984..
  • 4顾浚祥.现代物理研究方法及其在腐蚀科学中的应用[M].北京:化学工业出版社,1988..

二级参考文献16

  • 1王永霞,薛奇.表面增强拉曼光谱研究高分子-金属界面结构[J].化学通报,1995(1):5-10. 被引量:4
  • 2Hackerman N. Review of corrosion inhibition science and technoloy. Materials Performance, 1990,29(2): 44~ 47
  • 3Brubaker G P,Phipps P B. Corrosion Chemistry. Washington D C: American Chemical Society, 1979. 288 ~307
  • 4Fox P G,Lewis G,Boden P J. Some chemical aspects of the corrosion inhibiton on copper by benzotriazole. Corrosion Science, 1979,19(10): 457~467
  • 5Kim H, Jang J. Synthesis and characterization of vinyl silane modified imidazole copolymer as a novel corrosion inhibitor. Polymer Bulletin, 1997,38,249~ 256
  • 6Sekine I,Sanbongi M,Hagiuda H,et al. Corrosion inhibition of mild steel by cationic and anionic polymers in cooling water system. J Electrochem Soc, 1992,139 (11):3167~3173
  • 7Schweinsberg D P,Hope G A,Trueman A,et al. An electrochemical and SERS study on the action of polyvinylpyrrolidone and polyetvlenimine as inhibitors for copper in aerated H2SO4. Corrosion Science, 1996,38 (4): 587~ 599
  • 8Muralidharan S, Phain K L N, Pitchumani S, et al.Polyamino-benzoquinone polymers:a new class of corrosion inhibitors for mild steel. J Electrochem Soc, 1995,142(5): 1478~ 1483
  • 9Sitaram S P,Stoffer J O,Keefe T J. Application of conducting polymers in corrosion protection. J. of Coatings Technology, 1997,69(866); 65~ 69
  • 10Ahmad N, MacDiarmid A G. Inhibition of corrosion of steels with the exploitation of conducting polymers.Synthetic Metals, 1996,78:103 ~ 110

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