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全固态一氧化碳电化学传感器响应研究 被引量:8

Response of an electrochemical carbon monoxide sensor based on a solid polymer electrolyte
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摘要 采用化学还原方法制备了Pd Nafion复合膜电极作为催化传感电极 ,研制了室温全固态电解质型一氧化碳传感器 ,考察了复合膜电极对一氧化碳 /氮气体系产生电流响应的适宜电位 ,响应时间常数以及响应电流与一氧化碳体积分数的关系 。 A novel carbon monoxide sensor, based on a solid polymer electrolyte, which could be workable at room temperature was prepared. The sensing electrode was a Pd/Nafion membrane electrode prepared by a chemical deposition method. The suitable electricity between the two electrodes for the electrolysis of carbon monoxide in N 2 and the time constant were examined by a potentiostat. The relations between the sensor response current and the volume fraction of carbon monoxide in N 2 were discussed and the effect of the environmental temperature on the response current was also presented.
出处 《北京化工大学学报(自然科学版)》 CAS CSCD 2002年第4期59-61,71,共4页 Journal of Beijing University of Chemical Technology(Natural Science Edition)
关键词 全固态一氧化碳电化学传感器 定电位解分析 Pd-Nafion复合膜电极 响应时间常数 响应输出电流 carbon monoxide sensor electrolysis polymer membrane electrode
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  • 1[1]Bay H W, Blurton K F, Lieb H C, et al. Electrochemical measurement of carbon monoxide[J]. Amer Lab, 1972, 4(7): 57-58
  • 2[2]Yan Heqing, Liu Chung-Chiun. A solid polymer electrolyte-based electrochemical carbon monoxide sensor[J]. Sensors and Actuators B, 1994, 17: 165-168
  • 3[3]Kucernak A R, Muir B. Analysis of the electrical and mechanical time response of solid polymer-platinum composite membranes[J]. Electrochemical Acta, 2001, 46: 1313-1322
  • 4[4]Liu Raymond, Her Wei-hwa, Fedkiw Peter S. In situ electrode formation on a nafion membrane by chemical platinization[J]. J Electrochem Soc, 1992, 139(1):15
  • 5[5]Bay H W, Blurton K F, Sedlak J M, et al. Electrochemical technique for the measurement of carbon monoxide[J]. Anal Chem, 1974, 46: 1837-1839

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