摘要
采用纳米二氧化硅改性的羧甲基纤维素钠(CMC)-聚乙烯醇(PVA)/壳聚糖(CS)-PVA双极膜作为电槽隔膜,成对合成丁二酸和对氯苯甲醛。结果表明,最佳的合成条件为:电流密度60 m A/cm2,阴极室中硫酸浓度1.0 mol/L,对氯甲苯与Mn3+的摩尔比为4∶1。
The carboxymethyl cellulose （ CMC ）-polyvinyl alcohol （ PVA ）/chitosan （ CS ）-PVA bipolar membrane （ BPM） was modified by nano silicon dioxide. Then the modified BPM was used as electrolytic cell septum to synthesize succinic acid and p-chlorobenzaldehyde. The results showed that the optimal preparation conditions were as following：current density was 60 mA/cm2 , sulfuric acid concentration in the cathode chamber was 1. 0 mol/L,the molar ratio of p-chlorotoluene to Mn3＋ was 4∶1.
出处
《应用化工》
CAS
CSCD
北大核心
2015年第9期1687-1690,共4页
Applied Chemical Industry
基金
福建省自然科学基金项目(2013J01034)
福建省科技厅重点项目(2012H0019)
福州市科技局项目(2012-G-116)
关键词
双极膜
丁二酸
双氯苯甲醛
成对电合成
bipolar membrane
succinic acid
p-chlorobenzaldehyde
paired electrosynthesis
