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Preparation of CS-CMC Bipolar Membrane and its Application in Electro-generated FeO_4^(2-) 被引量:5

Preparation of CS-CMC Bipolar Membrane and its Application in Electro-generated FeO_4^(2-)
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摘要 CS-CMC bipolar membrane was prepared and the cross-section photograph of CS-CMC BM was observed by SEM. FT-IR spectrum indicated that CS-CMC BM contained -N=CRH2^+ and -COO^- functional groups. The charge density of -N--CRH2^+ in CS membrane was about 14.13 mmol/g and the charge density of -COO in CMC membrane was about 9.01 mmol/g. The electrochemistry properties of CS-CMC BM were also studied. CS-CMC BM not only can effectively stop FeO4^2- from diffusing into the cathode chamber, but also plays an important role in the supply of OH" consumed during the electro-generated FeO4^2- process. CS-CMC bipolar membrane was prepared and the cross-section photograph of CS-CMC BM was observed by SEM. FT-IR spectrum indicated that CS-CMC BM contained -N=CRH2^+ and -COO^- functional groups. The charge density of -N--CRH2^+ in CS membrane was about 14.13 mmol/g and the charge density of -COO in CMC membrane was about 9.01 mmol/g. The electrochemistry properties of CS-CMC BM were also studied. CS-CMC BM not only can effectively stop FeO4^2- from diffusing into the cathode chamber, but also plays an important role in the supply of OH" consumed during the electro-generated FeO4^2- process.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第11期1527-1530,共4页 中国化学快报(英文版)
关键词 Bipolar membrane (BM) cylinder electrolysis bath carboxymethylcellulose (CMC) chitosan (CS) ferrate (FeO4^2-) colloid titration. Bipolar membrane (BM), cylinder electrolysis bath, carboxymethylcellulose (CMC),chitosan (CS), ferrate (FeO4^2-), colloid titration.
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