摘要
二茂铁及其衍生物具有特殊的夹层状分子结构,因而具有诸多独特的物理和化学性质,在多个领域有着广阔的应用和研究价值。研究了对二茂铁进行乙酰化,制取1,1'-二乙酰基二茂铁的合成方法,并进而制备其氧化产物,制取1,1'-二茂铁二甲酸,并对合成条件进行优化。
Ferrocene and its derivatives have sandwich-like special molecular structure, so they have many unique physical and chemical properties, and have been studied and applied widely in many fields. In this paper, preparation process of 1,1＇-ferrocenedicarboxylic acid was studied, including synthesis of 1,1＇-diacetylferrocene by acetylation of ferrocene, and preparation of its oxidation products. At last, the synthesis conditions were optimized.
出处
《当代化工》
CAS
2015年第8期1774-1777,共4页
Contemporary Chemical Industry
基金
辽宁省教育厅科技攻关项目
项目号:L2011057
