期刊文献+

无皂乳液聚合制备单分散核-壳聚丙烯酸微粒 被引量:5

Preparation of Monodispersed Core-Shell Microspheres of Acryl Copolymer by Soap-Free Emulsion Polymerization
在线阅读 下载PDF
导出
摘要 The monodispersed copolymer microspheres were prepared by soap free emulsion copolymerization from methyl methacrylate(MMA), butyl acrylate(BA) and acrylic acid(AA). The microspheres have an average diameter d p=1 10 μm and monodispersity C v=2 02%. The monodispersed core shell copolymer microspheres having average diameter d p 1 14 μm and C v 1 18% were then prepared by seeding polymerization. It is confirmed from the number of seed microspheres and core shell microspheres that the polymerization of shell monomers was carried out only on the seed microspheres. The monodispersed copolymer microspheres were prepared by soap free emulsion copolymerization from methyl methacrylate(MMA), butyl acrylate(BA) and acrylic acid(AA). The microspheres have an average diameter d p=1 10 μm and monodispersity C v=2 02%. The monodispersed core shell copolymer microspheres having average diameter d p 1 14 μm and C v 1 18% were then prepared by seeding polymerization. It is confirmed from the number of seed microspheres and core shell microspheres that the polymerization of shell monomers was carried out only on the seed microspheres.
出处 《应用化学》 CAS CSCD 北大核心 2002年第6期606-608,共3页 Chinese Journal of Applied Chemistry
关键词 制备 无皂乳液聚合 核壳微粒 单分散性丙烯酸聚合物 soap free emulsion polymerization,core shell microsphere,monodisperse acryl copolymer
  • 相关文献

参考文献3

二级参考文献17

  • 1邱广明,孙宗华.水溶性磁流体的制备和性质[J].化学试剂,1993,15(4):234-237. 被引量:43
  • 2徐祖顺,张金枝,程时远.功能性阳离子聚合物乳液研究现状[J].功能高分子学报,1995,8(4):512-520. 被引量:19
  • 3林尚安 陆耘 等.高分子化学[M].北京:科学出版社,1983.600.
  • 4严昌虹 章贤明 等.-[J].化学试剂,1990,12(1):45-45.
  • 5邱广明 孙宗华.-[J].生物医学工程学杂志,1992,9(2):205-205.
  • 6Hung C T,Drug Dev Ind Pharm,1990年,16卷,3期,509页
  • 7Yan C H,J Appl Polym Sci,1990年,40卷,89页
  • 8Kitano H,Biopolymers,1989年,28卷,693页
  • 9林尚安,高分子化学,1982年,600页
  • 102,M.F.Hoover.J.MacromolSci.chem..1970,10,4(6):1327

共引文献17

同被引文献50

  • 1陈立,林静,林敏,黄海水.硫酸钡粉末存在下无乳化剂的聚合研究[J].高分子学报,1993,3(3):338-342. 被引量:8
  • 2范圣强,范一波,曹瑞军,周心艳,李长久.可聚合乳化剂改性对弹性丙烯酸酯乳液乳胶粒粒径的影响[J].化学建材,2004,20(6):11-13. 被引量:5
  • 3李昊,杨玉昆.无皂丙烯酸酯乳液压敏胶的制备与性能研究[J].粘接,2005,26(5):1-3. 被引量:10
  • 4ANN-CHARLOTTE HELLGREN,PETER WEISSENBOR,KRISTER HOLMBERG. Surfactants in water-bornepaints[J]. Progress in Organic Coatings,1999(35):79-87.
  • 5A GUYOT. Advances in reactive surfactants[J]. Advancesin Colloid and Interface Science,2004(108-109):3-22.
  • 6KIMIKO TAKAHASHI,KATSUTOSHI NAGAL Preparetion of reaction polymeric mierospheres by seeded copolymerization using a polymerizable surfaetant beating an active ester group[J], polymer, 1996,37(7) : 1257-1266.
  • 7阿方萨斯 V,波丘斯.粘结与胶粘剂技术导论[M].北京:化学工业出版社,2005:210.
  • 8S R TRENOR,A E SUGGS,B J LOVE. Influence of penetration enhancers on the thermomechanical properties and peel strength of a poly (isobutylene) pressuresensitive adhesive[J]. Journal of Materials Science Let-ters,2002(21 ) : 1 321-1 323.
  • 9Ann-Charlotte Hellgren, Peter Weissenborn, Krister Holm- berg. Surfactants in water-borne paints [ J ]. Progress in Or- ganic Coatings, 1999 (35) :79 - 87.
  • 10GUYOT A, Advances in reactive surfactants [ J ]. Advances in Colloid and Interface Science,2004 ( 108 - 109 ) :3 - 22.

引证文献5

二级引证文献28

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部