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具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究(英文)

Synthesis, Structure and Third-Order Nonlinear Optical Properties of a Planar Nickel Complex with Rigid Quadridentate Schiff Base Derived from S-benzyl Dithiocarbazate
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摘要 A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect. A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2002年第5期533-536,共4页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.20028101) 江苏省自然科学基金资助项目(No.BK99032)~~
关键词 平面结构 晶体结构 三阶线性光学 四齿肼基硫代甲酸苄酯 席夫碱 配合物 合成 nickel planar structure crystal structure third order nonlinear optics
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参考文献12

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