摘要
合成了联苯乙酮缩肼基双硫代甲酸苄酯及其铅(Ⅱ)的配合物,通过元素分析、摩尔电导率、红外光谱、电子光谱等进行了表征,证明了配体通过甲亚胺基氮原子和硫原子以烯醇式与二价铅离子配位,形成四配位的四面体构型配合物。
The new ligand 4-acetylbiphenyl-S-benzyldithiocarbonate and its Pb(Ⅱ) complex have been synthesized and characterized by elemental analysis,molar conductance,infrared and electronic spectraThe above analyses support a four-coordinate tetrahedron structure for the Pb(Ⅱ) complex with the ligand acting as bidentate chelating agent bonding the metal ion via the azomethine nitrogen atom and the thiol sulphur atom
出处
《化学试剂》
CAS
CSCD
1998年第2期74-75,92,共3页
Chemical Reagents