摘要
本文用循环伏安法和重差法分别测定了 NdF_3-LiF-CaF_2熔体中氧化钕电解的阴极过程;金属钕在该熔体中的溶解损失;在120～300安培级电解槽中进行了氧化钕电解试验,并将所得的电解指标与氯化钕电解法进行了对比分析。
Linear potential sweep experimental results show that in the moltensalt system of NdF_3-LiF-CaF_2 and NdF_3-LiF-CaF_2-Nd_2O_3 the electrochemicalreduction of Nd_1^(3+) at Mo cathode takes place in two steps:Nd^(3+)+e=Nd^(2+);Nd_-^(2+)+e=Nd.The loss of metallic Nd in fluorides melts under differentconditions was determinded according to the weight difference of Nd beforeand after experiments.
关键词
氧化钕
电解
熔盐
阴极过程
Electrolysis of Neodymium Oxide
Molten Salt
Loss of metal
Neodymium
Cathodic process
