摘要
合成了 2种草酰胺桥联的新异双核配合物 [Cu(Me2 oxpn)Mn(tmen) 2 ](ClO4 ) 2 (Ⅰ)和 [Cu(Me2 oxpn)Zn(bpy) 2 ](ClO4 ) 2 (Ⅱ) .其中 ,tmen和bpy分别代表N ,N ,N′,N′_四甲基乙二胺和 2 ,2′_联吡啶 ;Me2 oxpn为N ,N′_双(3_氨基_2 ,2_二甲基丙基 )草酰胺根阴离子 .用元素分析、红外光谱、电子光谱、摩尔电导及磁性测量等方法对配合物进行了表征 .
Two new μ-oxamido heterobinuclear complexes [Cu(Me 2oxpn)Mn(tmen) 2](ClO 4) 2 (Ⅰ), and [Cu(Me 2oxpn)Zn(bpy) 2](ClO 4) 2 (Ⅱ), where tmen and bpy stand for N,N,N′,N′-tetramethylenediamine and 2,2′-bipyridine, respectively; Me 2oxpn represents N,N′-bis(3-amino-2,2-dimethylpropyl)oxamido dianion, have been synthesized and characterized by elemental analyses, magnetic moment and molar conductivity measurements, UV and IR. The effects on the wheat growth of the binuclear complexes were also studied.
出处
《曲阜师范大学学报（自然科学版）》
CAS
2002年第1期69-72,共4页
Journal of Qufu Normal University(Natural Science)
基金
山东省自然科学基金资助项目 (Q99B12 )
