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多组分电解质溶液热力学体系HCl活度系数的测定 被引量:1

Determination of Activity Coefficient of HCl within the Thermodynamic System of Multicomponent Dielectric Solution
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摘要 用emf方法测定了五个温度下总离子强度I恒定为 0 .5 ,1.0 ,2 .0 ,3 .0 ,4.0和 5 .0mol·kg-1时的HCl -NiCl2 -C3H7OH -H2 O体系的HCl的活度系数。实验结果表明 ,在温度 5 ,15 ,2 5 ,35和 45℃时HCl的活度系数rA 能较好地符合Harned规则。 The paper determines the activity coefficient of HCl within HCl-HiCl-C\-3H\-7OH-H\-2O system with the EMF method~ under five temperature ranges and gross ionic strength I identified with 0.5,1.0,2.0,3.0,4.0 and 5.0 mol.Kg\+\{-1\} respectively.The result of t^he experiments shows that the activity coefficient of HCl,γ\-A,is in accord~ with~ Harned rule at temperature 5,15,25,35 and 45 Crespectively.
作者 郑溪娟
出处 《本溪冶金高等专科学校学报》 2000年第4期17-19,共3页 Journal of Benxi College of Metallurgy
关键词 电动势法 活度系数 HARNED规则 氯化氢 电解质溶液 Method of electromotive force Activity coefficient of HCl Harned rule
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  • 1Rabindra N. Roy,James J. Gibbons,David P. Bliss,Richard G. Casebolt,Bradley K. Baker. Activity coefficients for ternary systems: VI. The system HCl + MgCl2 + H2O at different temperatures; application of Pitzer’s equations[J] 1980,Journal of Solution Chemistry(12):911~930
  • 2Roger G. Bates,R. A. Robinson. Standardization of silver-silver chloride electrodes from 0 to 60°C[J] 1980,Journal of Solution Chemistry(7):455~456
  • 3D. Richard White,R. A. Robinson,Roger G. Bates. Activity coefficient of hydrochloric acid in HCl/MgCl2 mixtures and HCl/NaCl/MgCl2 mixtures from 5 to 45°C[J] 1980,Journal of Solution Chemistry(7):457~465

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