期刊文献+

乙醇——水混合溶剂中CuCl_2平均活度系数的研究

The Study of Activity Cofficient of CuCl_2 with CuCl_2-C_2H_5OH-H_2O System
在线阅读 下载PDF
导出
摘要 用电动势法测定了五个温度下总离子强度I恒定为0.2,0.4,0.6,0.8,1.0mol·Kg-1时CuCl2在乙醇——水混合溶剂中的平均活度系数,实验结果表明,在温度10℃,15℃,20℃,25℃和30℃时,CuCl2的活度系数能较好地符合Harned规则. The activity coefficient of CuCl2 within CuCl2-C2H5OH-H2O system are tested with the EMF under five temperature ranges and grossionic strength I identifyied with 0.2,0.4,0.6,0.8,1.0 mol·kg^-1 respectively. The result of the experiments shows that the activity coefficient of CuCl2 is in accord with Harned rule at temperature 10℃,15℃,20℃,25℃ and 30℃ respecively.
作者 黄中强
出处 《玉林师范学院学报》 2007年第3期33-34,38,共3页 Journal of Yulin Normal University
关键词 平均活度系数 电动势法 HARNED规则 activity coefficient Method of Electromotive Force Harned rule
  • 相关文献

参考文献9

二级参考文献13

  • 1[1]Kundu, kiron, K; chattopadyay, P· K; Das Mihihir N. (Hys. chen. Lab ,JabaVPur tmiv .Ealcutla, India) [J ]. chem. Eng.Data. 1970 (15 ): 209.13 (Eng)
  • 2[4]R·G·Bates and R·A·Robioson, [J]. sotution chem 1980(g): 455
  • 3[5]H· S· Harnecl and R· A· Robinson, MulticomPonent Electrohte solutions, Pergamon. OXford, 1968.
  • 4Robinson R A, Stokes R H. Electrolyte Solutions, 2nd Ed., Butterworths, Boston, MA,1959.
  • 5Pitzer K S. Accounts of Chem. Res. ,1977, 10:371.
  • 6Pitzer K S. J. Phys. Chem. , 1973, 77- 268.
  • 7YuYangxin(于养信) LuJiufang(陆九芒) LiYigui(李以圭).清华大学学报(自然科学版)),1995,35(3):59-59.
  • 8Rabindra N. Roy,James J. Gibbons,David P. Bliss,Richard G. Casebolt,Bradley K. Baker. Activity coefficients for ternary systems: VI. The system HCl + MgCl2 + H2O at different temperatures; application of Pitzer’s equations[J] 1980,Journal of Solution Chemistry(12):911~930
  • 9Roger G. Bates,R. A. Robinson. Standardization of silver-silver chloride electrodes from 0 to 60°C[J] 1980,Journal of Solution Chemistry(7):455~456
  • 10D. Richard White,R. A. Robinson,Roger G. Bates. Activity coefficient of hydrochloric acid in HCl/MgCl2 mixtures and HCl/NaCl/MgCl2 mixtures from 5 to 45°C[J] 1980,Journal of Solution Chemistry(7):457~465

共引文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部