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BF_3·Et_2O/MCM-41固体酸催化剂及其催化性能的研究 被引量:1

Studies on the BF_3·Et_2O/MCM-41 Solid Acid Catalyst and Its Catalytic Performance
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摘要 A solid acid catalyst has been prepared by grafting Boron trifluoride on mesoporous molecular sieve MCM 41 and characterized by XRD and FTIR techniques. The XRD and FTIR results indicated that the BF 3·Et 2O interlocks with the silicon groups of MCM 41 surface to form strong solid acid. The solid acid catalyst would effectively promote the opening of epichlorohydrin with isobutanol to form 1 isobutoxy 3 chloropropanol, and showed a nice activity and selectivity. A solid acid catalyst has been prepared by grafting Boron trifluoride on mesoporous molecular sieve MCM 41 and characterized by XRD and FTIR techniques. The XRD and FTIR results indicated that the BF 3·Et 2O interlocks with the silicon groups of MCM 41 surface to form strong solid acid. The solid acid catalyst would effectively promote the opening of epichlorohydrin with isobutanol to form 1 isobutoxy 3 chloropropanol, and showed a nice activity and selectivity.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第9期1576-1577,共2页 Chemical Journal of Chinese Universities
基金 浙江省自然科学基金 (批准号 :2 97770 0 5 )资助 .
关键词 BF3·Et2O/MCM-41 环氧氯丙烷 异丁醇 缩合反应 1-异丁氧基-3-氯异丙醇 固体酸催化剂 催化性能 BF 3·Et 2O/MCM 41 Epichlorohydrin Isobutanol Condensation reaction 1 Isobutoxy 3 chloropropanol
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