摘要
用甲基超共轭模型和多电子共轭的经验公式及合理的键积分参数K,计算了Baker-Nathan顺序中烷基的超共轭能,探讨了超共轭的本质。
Hyperconjugated energy of alkyl in the Baker-Nathan's order was calculated, by using the hyperconjugated model of methyl group, the experimental formula of many-electrons conjugative and rational bond integral parameter K. Essence of hyperconjugated effect was also approached.
关键词
B-N顺序
烷基
键参数
超共轭效应
hyperconjugated model of methyl group, hyperconjugated effect, bond integral parameter, Baker-Nathan's order