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碱土金属氧化物对焦炭溶损反应的催化作用研究 被引量:5

EFFECT OF ALKALI EARTH METAL OXIDES ON KINETIC PARAMETERS OF COKE SOLUTION LOSS REACTION
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摘要 Using a Temperature Programmed Reaction (TPR) technique, Gujiao coke loaded with alkali earth metal oxides were reacted with CO 2 The results indicated that BaO, CaO, MgO have positive catalysis on coke solution loss reaction and the catalytic order is: BaO > CaO > MgO Reactions with different oxides have different kinetic parameters All kinetic parameters (initial reaction temperature, activation energy, pre exponential) but reaction order are changed with the increase of catalyst content There is a compensation effect between activation energy and the pre exponential factor [WT5H1] Using a Temperature Programmed Reaction (TPR) technique, Gujiao coke loaded with alkali earth metal oxides were reacted with CO 2 The results indicated that BaO, CaO, MgO have positive catalysis on coke solution loss reaction and the catalytic order is: BaO > CaO > MgO Reactions with different oxides have different kinetic parameters All kinetic parameters (initial reaction temperature, activation energy, pre exponential) but reaction order are changed with the increase of catalyst content There is a compensation effect between activation energy and the pre exponential factor [WT5H1]
出处 《燃料化学学报》 EI CAS CSCD 北大核心 2001年第3期280-282,共3页 Journal of Fuel Chemistry and Technology
关键词 焦炭 矿物质 溶损反应 动力学 碱土金属氧化物 炼焦 催化作用 coke mineral solution loss reaction kinetic
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参考文献4

二级参考文献5

  • 1徐继军,1988年
  • 2张青林,催化学报,1988年,9卷,14页
  • 3张春林,催化学报,1988年,9卷,131页
  • 4徐继军,燃料化学学报,1991年,19卷,156页
  • 5Wen Y W,Rev Sci Eng,1980年,22卷,1页

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