摘要
本文应用穆斯堡尔谱对结晶紫与三氯化铁生成的络合物进行研究,得知络合物结晶紫的电子组态发生了变化,结合X射线光电子能谱、红外光谱的测量,我们认为结晶紫分子中N原子的孤对电子进入Fe^(3+)的外层轨道,形成类似于施受复合物的物质,改变了结晶紫的性质。
The Mossbauer effect combined with XPS, IR and X-ray diffraction, was used to study the complex of crystal violet and ferric chloride. After complexing, the electronic configuration is changed. The lone pair electron of nitrogen atom in crystal violet molecule transfers into the outer orbit of Fe3+ ion forming a substance which is similar to donor-acceptor complex. Therefore, the properties of crystal violet are varied.
出处
《核技术》
CAS
CSCD
北大核心
1991年第9期520-524,共5页
Nuclear Techniques
关键词
结晶紫
络合物
电子结构
Crystal violet Complex Mossbauer effect Electronic configuration Absorber
