摘要
作者以 Sm Cl3 与 (CH3 Cp) Na反应分离得到了三价稀土有机配合物 [(CH3 Cp) 2 Sm Cl·THF]2 的单晶 ,X-射线四圆衍射测定 ,该配合物属正交晶系 ,Pbna空间群 ,晶胞参数 a=9.6 6 2 (2 ) ,b=16 .4 76 (9) ,c=2 0 .582 (9) ;α=β=γ=90°,Z=4。并分析比较 [(CH3 Cp) 2 Sm Cl· THF]2
The complex, (CH 3Cp) 2SmCl·THF, has been synthesized by the reaction of SmCl 3 with two equivalents of CH 3CpNa. (CH 3Cp) 2SmCl·THF crystallized from THF in the rhombic space group P bna with cell constants a=9.662(2), b=16.476(9), c= 20.582(9) ; α=β=γ=90°, V=3276.5 3 ,and D o=1.69g/cm3 for Z=4. Least squares refinement of 2450 unique observed reflections led to a final R of 0.0518. We also compared the structural character of the complex with other trivalent organolanthanide chloride complexes.
出处
《青岛海洋大学学报（自然科学版）》
CSCD
北大核心
2001年第2期173-178,共6页
Journal of Ocean University of Qingdao
