摘要
建立了碲共沉淀分离富集、电感耦合等离子体原子发射光谱法（ICP-AES）测定铜灰渣样品中微量元素金、铂、钯的方法。研究了影响测量的各种因素，确定了最佳测定条件。方法的检出限为：Au 5.6μg/L、Pd 8.2μg/L、Pt 3.6μg/L，回收率93.2%-102%，相对标准偏差（RSD）为：1.21%（Au）-3.45%（Pd），方法测定结果与火试金法一致。方法准确、简便快速，易于掌握。
An analysis method for determination of gold, platinum and palladium in copper slag by inductively coupled plasma atomic emission spectrometry （ICP-AES） with tellurium co-precipitation separation and enrichment was developed. The factors affecting determination were investigated, and the optimal detection conditions were determined. The detection limits were 5.6 （Au） μg/L,8.2 （Pt） μg/L and 3.6 （Pd） μg/L, the recovery ratio was 93.2%-102%, the relative standard derivation （RSD） was 1.21%（Au）-3.45% （Pt）. The determination results were in good agreement with fire assaying. The method was accurate, simple and fast, and easy to master.
出处
《贵金属》
CAS
CSCD
北大核心
2014年第2期59-63,共5页
Precious Metals
关键词
分析化学
共沉淀分离
铜灰渣
金
铂
钯
ICP-AES
analytical chemistry
co-precipitation separation
ICP-AES
copper slag
gold
platinum
palladium
