摘要
本文介绍应用ＩＣＰ－ＡＥＳ法测定催化剂中Ｐｔ和Ｐｄ的分析方法，干扰元素的去除采用巯基棉柱分离法，这是基于在ＨＣＩ浓度达３ｍｏｌ／Ｌ时，巯基对Ｐｄ和Ｐｔ离子仍具有较强的吸附力。实验选定了最佳吸附酸度和洗脱条件，Ｐｄ的回收率为９１．３～１０６％，Ｐｔ的为９２～１０３％。
A method for the determination of Pd and Pt in catalyst by ICP--AES is introduced.Sulfhydryl cotton column is used to separate interferential elements based on the strong combination between Pd2+ (or Pt2+ )and sulfhydryl in 3 mol/L HCI concentration. The best separation condition is selected. Recoveries of Pd and Pt are 91. 3￣106 % and 92￣103 % respectively.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1994年第5期55-58,共4页
Spectroscopy and Spectral Analysis
