摘要
采用水合煅烧法结合反应动力学方程对试验室烧制的氧化钙膨胀熟料的水化动力学过程进行了描述,并采用XRD、SEM等相关微观测试手段对其矿物组成及微观结构进行了测试分析。结果表明:氧化钙膨胀熟料中的f-CaO在纯水中的水化反应符合Avrami等温结晶动力学模型,其水化程度随反应温度的升高而增大,水化反应速率常数和温度的关系符合Arrhenius定律;氧化钙膨胀熟料粉体中除含有独立的f-CaO颗粒外,还含有大量于同一颗粒中同时存在f-CaO、无水石膏、硫铝酸钙(部分尚含有硅酸钙等)矿物相的颗粒,氧化钙膨胀熟料中f-CaO的水化活性与纯CaO以及包裹于水泥熟料或高钙粉煤灰中的f-CaO不同。
Hydrating and calcining method combined with the kinetic equation were adopted to describe the hydration kinetics process of the laboratory-calcined CaO expansion clinker,XRD and SEM were used to test and analysis its mineral compo-sition and microstruc- ture as well.The results show that, hydration reaction process in pure water of f-CaO contained in the CaO expansion clinker meets the Avrami isothermal crystallization kinetics model, and the hydration degree increases with temperature, with the relation between reaction rate constant and temperature conforming to Arrhenius law; the CaO expansion clinker powder contains a large number of particles in which f-CaO, CaSO4, Ca^A16012SO4（partly still containing calcium silicates ） phases existing at the same time, by the impact of the presence of impurity phases and the difference of calcining conditions, the hydration activity of f-CaO contained in CaO expansion clinker was different from that of pure CaO and that of f-CaO wrapped in cement clinker or high-calcium fly ash.
出处
《混凝土》
CAS
CSCD
北大核心
2014年第3期75-78,83,共5页
Concrete
基金
国家杰出青年科学基金(51225801)
国际科技合作计划-中以合作项目(BZ2012003)
关键词
氧化钙膨胀熟料
水化动力学
微观分析
calcium oxide expansion clinker
hydration kinetics
microscopic analysis
